1,290 Result(s)
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Chapter and Conference Paper
Some Aspects of the Theory of Atom-Bridge Bonds
An atom may form a bridge-bond between two other atoms, when it con — siderably differs in electronegativity. There are two extreme examples of such type of bond: X-H -X hydrogen bond and X -O -X (1) oxygen bond.
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Chapter and Conference Paper
The Electronic Spectra, Optical Rotatory Power, and Absolute Configuration of O-Phenanthroline and 2,2′-Dipyridyl Complexes
The present work reports the circular dichroism spectra and the unpolarized light absorption of the tris-2, 2′-dipyridyl and the tris-1,10-phenanthroline complexes of Ni(II), Fe(II), Ru(II), Os(II), Ru(III) an...
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Chapter and Conference Paper
Industrial Applications of Microprobe Analysis
Electron probe X-ray microanalysis has revealed a new realm of analytical investigations on a microscopic scale. But while the microprobe permits high precision in strictly quantitative analysis, such precisio...
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Chapter and Conference Paper
Color and Variable Valence in Niobium and Tantalum Halides
The very stable polynuclear halide ions [M6X12]2+ (M = Nb or Ta, X = Cl or Br) are unique in that though the X-ray structure analyses of the complex (Fig. 1) demonstrate that the metal ions are all in equivalent ...
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Chapter and Conference Paper
Complex Formation by Molybdenum(II)Chloride
Comparison of the ultra-violet reflectance spectrum of Mo(II)chloride with that of the acid H2[Mo6Cl8. Cl6]. 8 H2O (1) which has an Mo6Cl8 cage confirms the close structural similarity of the chloride. It seems c...
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Chapter and Conference Paper
Mössbauer Spectra of Iron Complexes with Thiosemicarbazone of Diacetyloxime and their Interpretation
The use of Mössbauer effect permits to investigate the displacements of the electronic cloud arising due to the chemical changes in the molecule. Mössbauer spectra were obtained for iron compounds given below....
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Chapter and Conference Paper
Crystal Structures of Some Compounds Containing Bonds between Dissimilar Metal Atoms
In the last few years many compounds have been synthesised in which two, or more, metal atoms are linked. It has been known for some time that atoms of the same metallic element are joined together in sone com...
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Chapter and Conference Paper
Chemical Structure Determination of Lantanides’ Coordination Compounds on the Basis of Their Absorption Spectra
Heretofore the majority of investigators considered the chemical bond in coordination compounds of the rare earths elements to be of ionic nature. Within the last years, however, many arguments have been submi...
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Chapter and Conference Paper
Schlußwort
Meine Damen und Herren, wir haben in diesen Tagen eines unserer fruchtbarsten Colloquien zum Abschluß gebracht. Es war ein ausgezeichneter Gedanke, die letzten Ergebnisse der theoretischen organischen Chemie i...
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Chapter and Conference Paper
Über Die Katalytische Wirksamkeit von Übergangsmetall-π-Allylverbindungen
Bei der Umsetzung von Übergangsmetallverbindungen mit metallorgani — schen Verbindungen, wie z. B. Aluminiumalkylen, entstehen im allgemeinen instabile Übergangsmetallalkyle bzw.-aryle, deren Metall-Kohlenstof...
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Chapter and Conference Paper
Transition Metal Complexes of Caged Phosphite Esters
The unusual donor abilities of caged phosphites {Ia} and {III} have been the subject of recent investigations in these laboratories. The low steric requirements and high dipole moments of {Ia} and {II} are und...
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Chapter and Conference Paper
The catalytic site and mechanism of action of bovine pancreatic ribonuclease
Bovine pancreatic ribonuclease is the only enzyme for which the primary structure is known (Hirs, Moore and Stein, 1960; Smyth, Stein and Moore, 1962; Potts et al., 1962; Gross and Witkop, 1962). The nature of th...
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Chapter and Conference Paper
Soft and Very Soft Fluorescence Analysis: Spectrographic and Electronic Modifications for Optimum, Automated Results
The use of soft X-ray sources (designed by B. L. Henke, Pomona College) in a commercial vacuum spectrograph requires modifications in the optic path dependent upon the wavelength region being considered. Chang...
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Chapter and Conference Paper
The Direct Gas Chromatographic Determination of Low Molecular Weight Fatty Acids in Rumen Fluid
A gas chromatographic procedure to analyze rumen fluids for the low molecular weight fatty acids through n-valeric acid has been developed. The method requires little pretreatment of the rumen sample. The colu...
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Chapter and Conference Paper
Entwicklung und präparative Möglichkeiten der Carben-Chemie
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Chapter and Conference Paper
The chemistry and function of ferredoxin
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Chapter and Conference Paper
A Blazed-Grating Scanning Spectrometer for Ultrasoft X-Rays Suitable for Use in an Electron Microprobe
The importance of operating within the blaze angle is emphasized by a series of measurements of ultrasoft X-rays obtained with a new grazing-incidence, grating spectrometer. A formula to maximize output intens...
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Chapter and Conference Paper
Biosynthesis of Phoshoinositides
It is now known that brain contains three phosphoinositides, a monophosphoinositide (MPI)* a diphosphoinositide (DPI) and a triphosphoinositide (TPI) (Hörhammbr, Wagner, and Hölzl, 1958, 1960; Brockerhoff and Bal...
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Chapter and Conference Paper
Automated Peptide Synthesis
The value of synthetic organic chemistry to our understanding of the action of hypotensive peptides, and other biologically active peptides, has been well demonstrated. For example, the structure of bradykinin...
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Chapter and Conference Paper
Cardiovascular Actions of Physalaemin
Physalaemin and eledoisin and perhaps substance P belong to a group of peptides having similar pharmacological actions (Bertaccini et al., 1965a,b) both in vitro and in vivo. In vivo, these peptides affect the...