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Article
Quenching of the fluorescence of riboflavin by the histidinates and alaninates of nickel, copper, and zinc
The formation of complexes of histidinates and alaninates of Ni(II), Cu(II), and Zn(II) with riboflavin (RF) in the ground state and the quenching of the fluorescence of RF by these compounds has been investig...
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Article
Interaction of the macrocyclic polyether dibenzo-18-crown-6 with the lanthanide shift reagent Eu(fod)3
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Article
Lanthanide-ion-induced paramagnetic shifts in NMR spectra in aqueous solutions
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Article
The correlation between the nephelauxetic effect in mono-Β-diketonates of europium and the inductive properties of the substituents in the 3-diketones
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Article
The use of paramagnetic shifts, induced by lanthanide shift reagents, to study the kinetics for ligand exchange
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Article
Investigation of the coordination properties of esters of phosphonecarboxylic acids by the PMR method, using lanthanide shift reagents
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Article
Composition and stability of adducts of the lanthanide shift reagent Pr(FOD)3 with hexamethylphosphoramide
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Article
Estimation of limiting shifts and stability constants of adducts of lanthanide shift reagents with hexamethylphosphoramide
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Article
Regularities of band shifts in spectra of lanthanide ions upon complex formation in solutions
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Article
Angular parameters of the overlap integrals of f-orbitals
Angular parameters are calculated for these integrals for σ- and π-types in the complexes MX6 (Oh and D3h symmetry), MX8 (Oh, D4d, D2d, D6h, C2V, and D3h), and MX9 (D3h). Examples are given of the use of the angu...
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Article
Investigation of the absorption spectra of europium benzoylacetonate complexes in methanolic and aqueous methanolic solutions
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Article
Luminescence spectra of chelate compounds of europium in aqueous methanol solutions
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Article
The long-wave displacement of the bands in the spectra of complex compounds of the rare earth elements
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Article
Relationship between the long-wave shift of the bands in the spectra of rare earth complexes and their structure
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Article
Deduction of structures of lanthanoid coordination compounds from absorption spectra
The nepheloxetic effect (reduction in the electron repulsion parameter B in a coordination compound relative to that in the gaseous ion) indicates that the bond type deviates from ionic. There is a linear rela...
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Chapter and Conference Paper
Chemical Structure Determination of Lantanides’ Coordination Compounds on the Basis of Their Absorption Spectra
Heretofore the majority of investigators considered the chemical bond in coordination compounds of the rare earths elements to be of ionic nature. Within the last years, however, many arguments have been submi...