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  1. No Access

    Chapter and Conference Paper

    Basic Parameters in Metal-Catalysed Processes: The “Method of Inverse Titration”

    The formalisms of Ni-catalysed organic syntheses using alkenes, alkynes, 1, 3-dienes and 1, 3, 5-trienes or their heteroanalogous substrates are compared with those of enzyme chemistry. For the unevolved metal...

    P. Heimbach, J. Kluth, H. Schenkluhn in Catalysis in Chemistry and Biochemistry Th… (1979)

  2. No Access

    Chapter

    Nickel Catalysed Syntheses of Methyl-Substituted Cyclic Olefins, an Example of Stepwise Carbon-Carbon Bond Formation Promoted by a Transition Metal Complex

    The cyclotrimerization of buta-l,3-diene to cyclododeca-l,5,9-triene was discovered by G. Wilke in 1956 during an investigation concerned with the effect of titanium and chromium containing Ziegler catalysts o...

    P. Heimbach in Aspects of Homogeneous Catalysis (1974)

  3. No Access

    Chapter and Conference Paper

    Über Die Katalytische Wirksamkeit von Übergangsmetall-π-Allylverbindungen

    Bei der Umsetzung von Übergangsmetallverbindungen mit metallorgani — schen Verbindungen, wie z. B. Aluminiumalkylen, entstehen im allgemeinen instabile Übergangsmetallalkyle bzw.-aryle, deren Metall-Kohlenstof...

    G. Wilke, P. Heimbach, B. Bogdanović… in Proceedings of the 8th International Confe… (1964)