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Article
Synthesis of Highly Dispersed 2D Aluminum Cobalt Oxyhydroxide Compounds Based on Microwave-Activation Products of Crystalline Gibbsite
We have studied interaction between the microwave activation product of gibbsite and an aqueous cobalt nitrate solution at room temperature, atmospheric pressure, and pH 8.0 ± 0.3. The results demonstrate that...
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Article
Sol–gel synthesis of 2D and 3D nanostructured YSZ:Yb3+ ceramics
This paper presents results of a detailed study of fundamental aspects of the formation of 2D and 3D nanostructured YSZ:Yb3+ ceramics with a cubic structure through a key synthesis step in aqueous solutions of zi...
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Article
Synthesis, electronic state, and particle size stabilization of nanoparticulate [Co(OH)2(H3O) δ + ]δ+
We have synthesized nanoparticulate cobalt(II) hydroxide containing Co2+ in tetrahedral oxygen coordination (Co Td 2+ ), atypi...
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Article
Complete-profile analysis applied to nonstoichiometric spinels
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Article
The unusual morphological structure of the aging products of coprecipitated Fe(III)-Al(III) hydroxides
Aluminum-substituted hematite (α *-Fe2O3) with an unusual morphological structure is formed upon the aging of coprecipitated Fe(III)-Al(III) hydroxides with excess Fe(III). The crystals of this hematite are found...
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Article
Effect of production conditions on physicochemical properties of aluminum and magnesium hydroxides
A study has been made of the effect of production conditions on chemical and phase composition, morphological structure, and surface area of aluminum and magnesium hydroxides synthesized in “equilibrium” and “...
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Article
Investigation of the structural changes in bayerite during mechanochemical activation
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The mechanochemical activation of bayerite is accompanied by displacement of the hydroxyl units followed by s...
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Article
Kinetics of kaolinite dehydration and its dependence on mechanochemical activation
For the mechanochemical activation of two processes can be considered: the structural disordering of laminar crystals, and the formation of molecular dense aggregates from small particles. The activation energ...
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Article
Reaction of anions of original salts with products of hydrolytic polymerization of Al(III) aquo ions
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During polymerization of aquo ions of Al(III), nitrate and chloride ions take part in the formation of sol pa...
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Article
Variation of the composition of the polymerization products of Al(III) aquo ions with the initial solution concentration
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At the same ratio of the added base to the metal (ϰ = 1.9) the composition of the polynuclear complexes and t...
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Article
Characteristics of hydrolytic polymerization of metal aquo-ions in mixed aqueous solutions of Fe(III)-Al(III) salts
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The process for the polymerization of metal aquo-ions in mixed aqueous solutions of Fe and Al salts can be su...
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Article
Structure and properties of primary polymer particles of freshly precipitated Cr3+ hydrogels
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Freshly precipitated hydrogels of Cr3+ have a number of structural hydroxyl groups per single cation correspo...
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Article
Some peculiarities of the mechanism of the hydrolytic polymerization of Fe3+ ions in aqueous solution
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Certain peculiarities of the mechanism of the polymerization of Fe3+ ions in aqueous solutions were investiga...
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Article
Investigation of the properties of primary polymer particles of freshly precipitated Fe3+ hydrogels
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A new approach to the investigation of freshly precipitated Fe3+ hydrogels, based on the concepts of the poly...
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Article
New variations of the chromatographic production of high-purity gases and vapors
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The production of especially pure substances using new variations of gas Chromatography-thermal displacement,...
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