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Article
Joint Cracking of Vacuum Gasoil with Vegetable Oils on Zeolite-Containing Catalysts of Various Compositions
The influence of the composition of a zeolite-containing catalyst on the target product distribution in joint cracking of vacuum gasoil with vegetable oils was studied. Introduction of ZSM-5 zeolite into the c...
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Article
Effect of Modification Conditions on the Physicochemical Characteristics of Y Zeolite as a Component of a Petrochemical Cracking Catalyst
This paper describes the investigation of the individual effects of the introduced quantities of rare-earth elements (REE) and of SiO2/Al2O3 ratio on the physicochemical characteristics (textural ...
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Article
Effect of Mixed Oxide Cracking Catalyst on Conversion of the Mixture of Vacuum Gas Oil and Vegetable Oil
A number of cracking catalyst samples containing Me–Mg–Al mixed oxides have been prepared. Cobalt, zinc, copper, and cerium were used as additional metals in the mixed oxide composition. When studyin...
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Article
Coconversion of n-Dodecane and 2-Methylthiophene in the Presence of Dual-Zeolite Cracking Catalysts Containing Different Amounts of Rare-Earth Elements
The effect of the rare-earth element (REE) content in dual-zeolite cracking catalysts on the conversion of n-dodecane and an n-dodecane–2-methylthiophene mixture (5000 ppm S) has been studied. The catalysts have ...
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Article
Conversion of Oil Shale Hydroconversion Products in the Presence of Supported Nickel–Molybdenum Sulfide Catalysts
The conversion of oil shale (OS) in a hydrogen medium at a pressure of 6.0 MPa and a temperature of 400°C with the subsequent refining of the resulting products in the presence of NiMo sulfide catalysts suppor...
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Article
Special Features of Cyclohexane Cracking over Dual-Zeolite Catalysts in the Presence of Sulfur and Nitrogen Compounds
Conversions of cyclohexane and cyclohexane mixtures with 2-methylthiophene (5000 ppm S) and pyrrole (500 ppm N) over dual-zeolite cracking catalysts have been studied. The catalysts have been synthesized using...
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Article
Catalytic Cracking of a Mixture of Vacuum Gas Oil and Vegetable Oil in the Presence of Mixed Mg–Al Oxide of Various Compositions
Effect of mixed Mg–Al oxides contained in catalysts on the distribution of target products formed in cracking of a mixture of vacuum gas oil with sunflower oil was examined. It was found that the process of de...
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Article
Effect of Phosphorus Modification of Zeolites Y and ZSM-5 on the Cracking of Hydrotreated Vacuum Gas Oil and a Vacuum Gas Oil–Sunflower Oil Mixture
The effect of the preliminary impregnation of zeolites HREY and HZSM-5 with ammonium phosphate before introducing them into the composition of dual-zeolite catalysts has been studied. It has been found that th...
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Article
Key Features of Cotransformation of Vacuum Gas Oils and Vegetable Oils on Dual-Zeolite Cracking Catalysts
The study of cotransformation of petroleum fractions with vegetable oils on dual-zeolite cracking catalysts has revealed that vegetable oils differing in fatty acid composition admixed to vacuum gas oil, chara...
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Article
Methods for Modifying a ZSM-5 Type Zeolite to Alter the Activity of the System of Hydrogen Transfer Reactions in the Cracking of Lower Aliphatic Alcohols
The influence of the alkali treatment of ZSM-5 zeolites with a silica ratio of 30 within the NaOH : SiO2 molar ratio of 0 : 230, as well as the modification of a ZSM-5 zeolite with phosphorus in the range of 0–8 ...
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Article
Cotransformations of n-Hexadecane, Hexene-1, and Cyclohexane over Dual-Zeolite Cracking Catalysts
Characteristic features of the conversion of n-hexadecane, hexene-1, cyclohexane, and their mixtures over dual-zeolite catalysts for co-cracking of light and heavy fractions are considered. The maximum yield of o...
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Article
Additives for Carbon Monoxide Afterburning in Gases from Regeneration of a Cracking Catalyst without Noble Metals
Additives for diminishing the content of carbon monoxide in gases formed in regeneration of the cracking catalyst without noble metals were synthesized and tested. As additives of this kind can serve mixed oxi...
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Article
The Formation of Properties of Ultrastable Zeolite Y for Cracking and Hydrocracking Catalysts
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Article
Main Approaches to Creating Nitrogen-Resistant Cracking Catalysts
Data are presented on the modification of cracking catalysts in order to improve their resistance to the poisoning effect of nitrous compounds of various classes. The modification of the catalyst matrix consis...
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Article
Butane–butylene fraction cracking over modified ZSM-5 zeolite
The effect of temperature (530–590°C), weight hourly space velocity (2.5–7.0 h–1), and the Si/Al ratio of the ZSM-5 zeolite (30, 55, 80, 300) on the cracking of a butane–butylene fraction containing 85 wt % butyl...
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Article
Features of combined conversion of naphthenic hydrocarbons and fatty acids under catalytic cracking conditions
The composition of the products of the combined conversion of various naphthenic hydrocarbons and fatty acids has been studied. It was determined that the distribution of the cracking products of model mixture...
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Article
Catalytic cracking of vegetable oils for production of high-octane gasoline and petrochemical feedstock
The routes of transformation of vegetable oils under catalytic cracking conditions have been investigated. The influence of the component composition of the catalyst on distribution of the desired cracking pro...
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Article
Influence of [H]-donating activity of hydrocarbons on transformations of thiophene compounds under catalytic cracking conditions
Transformations of 2-methylthiophene and benzothiophene together with n-undecane, declaim, or cumene under conditions of catalytic cracking have been studied. It has been found that enhancement of the [H]-donatin...
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Article
Fixation of vanadium and nickel compounds on mixed magnesium-aluminium oxide
The work discusses the mechanism of fixing vanadium and nickel compounds on mixed magnesium-aluminium oxide obtained from respective hydrotalcite. Using the diffuse reflectance of UV-Vis spectroscopy, it has b...
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Article
Conversion of nickel and vanadium porphyrins under catalytic cracking conditions
The conversion of nickel and vanadium porphyrins under conditions of catalytic cracking has been studied. Samples of porphyrins and their mechanical mixtures with a cracking catalyst have been investigated by ...