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Article
Structural and Catalytic Properties of Binary Alumina‒Amorphous Aluminosilicate Systems
Amorphous aluminosilicate‒alumina systems are investigated by a set of physicochemical means that includes studying the NMR 27Al spectra of solid samples and the acidity of catalysts via ammonia temperature-progr...
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Article
Phenol and Tetralin Co-Conversion Regularities under Catalytic Cracking Conditions
The effect of an oxygen-containing compound on the cracking of an aromatic hydrocarbon is studied using the example of a model phenol–tetralin mixture. An analysis of the temperature dependences of the crackin...
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Article
Effect of the Iron Oxide Content in Bentonite Clay Incorporated into a Catalytic System on the Sulfur Distribution in the Products of Cracking from Model Sulfur-Containing Feedstock
The effect of adding clay with different contents of iron oxides to a catalytic cracking system on the distribution of feedstock sulfur in synthesized products and the amount of sulfur oxides formed during the...
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Article
Joint Cracking of Vacuum Gasoil with Vegetable Oils on Zeolite-Containing Catalysts of Various Compositions
The influence of the composition of a zeolite-containing catalyst on the target product distribution in joint cracking of vacuum gasoil with vegetable oils was studied. Introduction of ZSM-5 zeolite into the c...
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Article
Effect of Modification Conditions on the Physicochemical Characteristics of Y Zeolite as a Component of a Petrochemical Cracking Catalyst
This paper describes the investigation of the individual effects of the introduced quantities of rare-earth elements (REE) and of SiO2/Al2O3 ratio on the physicochemical characteristics (textural ...
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Article
Effect of Mixed Oxide Cracking Catalyst on Conversion of the Mixture of Vacuum Gas Oil and Vegetable Oil
A number of cracking catalyst samples containing Me–Mg–Al mixed oxides have been prepared. Cobalt, zinc, copper, and cerium were used as additional metals in the mixed oxide composition. When studyin...
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Article
Coconversion of n-Dodecane and 2-Methylthiophene in the Presence of Dual-Zeolite Cracking Catalysts Containing Different Amounts of Rare-Earth Elements
The effect of the rare-earth element (REE) content in dual-zeolite cracking catalysts on the conversion of n-dodecane and an n-dodecane–2-methylthiophene mixture (5000 ppm S) has been studied. The catalysts have ...
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Article
Conversion of Oil Shale Hydroconversion Products in the Presence of Supported Nickel–Molybdenum Sulfide Catalysts
The conversion of oil shale (OS) in a hydrogen medium at a pressure of 6.0 MPa and a temperature of 400°C with the subsequent refining of the resulting products in the presence of NiMo sulfide catalysts suppor...
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Article
Special Features of Cyclohexane Cracking over Dual-Zeolite Catalysts in the Presence of Sulfur and Nitrogen Compounds
Conversions of cyclohexane and cyclohexane mixtures with 2-methylthiophene (5000 ppm S) and pyrrole (500 ppm N) over dual-zeolite cracking catalysts have been studied. The catalysts have been synthesized using...
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Article
Catalytic Cracking of a Mixture of Vacuum Gas Oil and Vegetable Oil in the Presence of Mixed Mg–Al Oxide of Various Compositions
Effect of mixed Mg–Al oxides contained in catalysts on the distribution of target products formed in cracking of a mixture of vacuum gas oil with sunflower oil was examined. It was found that the process of de...
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Article
Effect of Phosphorus Modification of Zeolites Y and ZSM-5 on the Cracking of Hydrotreated Vacuum Gas Oil and a Vacuum Gas Oil–Sunflower Oil Mixture
The effect of the preliminary impregnation of zeolites HREY and HZSM-5 with ammonium phosphate before introducing them into the composition of dual-zeolite catalysts has been studied. It has been found that th...
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Article
Key Features of Cotransformation of Vacuum Gas Oils and Vegetable Oils on Dual-Zeolite Cracking Catalysts
The study of cotransformation of petroleum fractions with vegetable oils on dual-zeolite cracking catalysts has revealed that vegetable oils differing in fatty acid composition admixed to vacuum gas oil, chara...
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Article
Methods for Modifying a ZSM-5 Type Zeolite to Alter the Activity of the System of Hydrogen Transfer Reactions in the Cracking of Lower Aliphatic Alcohols
The influence of the alkali treatment of ZSM-5 zeolites with a silica ratio of 30 within the NaOH : SiO2 molar ratio of 0 : 230, as well as the modification of a ZSM-5 zeolite with phosphorus in the range of 0–8 ...
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Article
Controlling the Ratio of the Reactions of Intermolecular Hydrogen Transfer and Cracking on Setups with Fixed and Recycled Catalyst Beds
The effect of the main parameters (temperature, pressure, and dilution of the reaction medium with an inert gas) of such catalytic processes as the cracking of vacuum gasoil and the hydrogenless refining and c...
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Article
Cotransformations of n-Hexadecane, Hexene-1, and Cyclohexane over Dual-Zeolite Cracking Catalysts
Characteristic features of the conversion of n-hexadecane, hexene-1, cyclohexane, and their mixtures over dual-zeolite catalysts for co-cracking of light and heavy fractions are considered. The maximum yield of o...
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Article
Additives for Carbon Monoxide Afterburning in Gases from Regeneration of a Cracking Catalyst without Noble Metals
Additives for diminishing the content of carbon monoxide in gases formed in regeneration of the cracking catalyst without noble metals were synthesized and tested. As additives of this kind can serve mixed oxi...
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Article
The Formation of Properties of Ultrastable Zeolite Y for Cracking and Hydrocracking Catalysts
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Article
Catalytic Cracking of Cyclohexane and 1-Hexene Mixtures on Mono-, Bi-, and Tri-Zeolite Catalysts
The effects of temperature (540–640°C), weight hour space velocity (1.0–7.0 h–1), and steam : raw material ratios (0–2.5) on the yield of C2–C4 olefins, conversion, and octane characteristics in the cracking of a...
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Article
Modifying Zeolite ZSM-5 to Increase the Yield of Light Olefins in Cracking Feedstocks of Petroleum and Vegetable Origin
The effect modifying the HZSM-5 zeolite contained in a bizeolite catalyst has on the conversion of hydrotreated vacuum gas oil, vegetable oil, and a vacuum gas oil–vegetable oil mixture under conditions of cat...
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Chapter and Conference Paper
NiMo/USY-Alumina Catalysts with Different Zeolite Content for Vacuum Gas Oil Hydrocracking Over Stacked Beds
The stacked beds comprising hydrotreating catalyst as the top layer, hydrocracking catalyst based on amorphous silica-alumina as the interlayer and hydrocracking catalyst based on USY zeolite as the bottom lay...