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Article
The Influence of Test Conditions for the Second Hydrocracking Stage Catalysts on the Time to Reach Steady-State Activity
Catalysts of the second stage of hydrocracking are tested under different conditions, reducing the time required to reach the level of steady-state activity. Tests are performed on a laboratory testbench under...
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Article
Dynamics of Silicon Sorption on the NiMo/Al2O3 Guard Bed Catalyst During Hydrotreating of Diesel
The dynamics of the silicon sorption on the NiMo/Al2O3 guard-bed catalyst containing ~2.0 wt % Ni and ~6.0 wt % Mo during hydrotreating of diesel was studied. The catalyst bed was divided into five equal sections...
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Article
Effects of Tar Hydrocracking on Subsequent Carbonization
The study investigated thermal carbonization of oil tar in comparison with tar carbonization over a Ni/Sibunit catalyst at 450–600°C. The addition of Ni/Sibunit to the tar slightly enhanced the yield of coke. ...
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Article
Conversion of Oil Shale Hydroconversion Products in the Presence of Supported Nickel–Molybdenum Sulfide Catalysts
The conversion of oil shale (OS) in a hydrogen medium at a pressure of 6.0 MPa and a temperature of 400°C with the subsequent refining of the resulting products in the presence of NiMo sulfide catalysts suppor...
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Article
Hydrogenation of Bituminous Sand
The effect of the conditions of bituminous sand hydrogenation on the yields and properties of the resulting liquid hydrocarbons was studied. It was found that, on the hydrogenation of bituminous sand, hydrocar...
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Article
Influence of Temperature on the Hydrogenation of Oil Shale from the Kashpir Deposit
The effect of the hydrogenation temperature of oil shale from the Kashpir deposit on the yield and the properties of the resulting liquid hydrocarbons and gasoline and diesel fractions separated from them was ...
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Article
Hydrocracking of Vacuum Gasoil on NiMoW/AAS-Al2O3 Trimetallic Catalysts: Effect of the W : Mo Ratio
The effect of the W: (W + Mo) atomic ratio in NiMoW trimetallic catalysts on their catalytic and physicochemical properties is studied. The catalysts are prepared by impregnating a carrier containing amorphous...
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Chapter and Conference Paper
NiMo/USY-Alumina Catalysts with Different Zeolite Content for Vacuum Gas Oil Hydrocracking Over Stacked Beds
The stacked beds comprising hydrotreating catalyst as the top layer, hydrocracking catalyst based on amorphous silica-alumina as the interlayer and hydrocracking catalyst based on USY zeolite as the bottom lay...
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Article
Hydrocracking of Vacuum Gasoil on NiMo/AAS-Al2O3 Catalysts Prepared from Citric Acid: Effect of the Catalyst Heat Treatment Temperature
Ni-Mo bimetallic catalysts are prepared by impregnating a carrier containing amorphous aluminosilicate (AAS) and aluminum oxide using a solution with Ni, Mo, and citric acid. The temperature of the catalysts r...
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Article
Hydroconversion of Oil Shale on Natural Mineral Matrices
The hydroconversion of high-sulfur oil shale in the presence of natural mineral matrices: shale ash, sandstone, and clay has been investigated. It has been shown that mineral matrices containing clays and iron...
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Article
Influence of the conditions of hydrogenation treatment of black oil on the yield and properties of the products obtained
The conversion of black oil in hydrogen (hydroconversion) and nitrogen (pyrolysis) media was studied. The influence of the hydrogen pressure and temperature of the hydrotreating of black oil on the yield and p...
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Article
Hydrocracking of vacuum gas oil in the presence of catalysts NiMo/Al2O3–amorphous aluminosilicates and NiW/Al2O3–amorphous aluminosilicates
Supported nickel–molybdenum and nickel–tungsten hydrocracking catalysts prepared using a support that consists of 70% Al2O3 and 30% amorphous aluminosilicate were characterized by nitrogen and mercury porosimetry...
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Article
A new catalyst for the deep hydrotreatment of vacuum gas oil, a catalytic cracking feedstock
A new CoNiMo/Al2O3 deep vacuum gas oil hydrotreatment catalyst designed for the production of catalytic cracking feedstocks containing 200–500 ppm of sulfur is developed. The method for its preparation includes t...
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Article
Vacuum gasoil hydrocracking over three-layered packages consisting of supported sulfide NiMo and NiW catalysts
A method for vacuum gas oil hydrocracking using a three-layered package of catalysts is proposed, in which the top layer is NiMo/Al2O3, the middle is NiM/AAS-Al2O3 and the bottom is NiM/Y-Al2O3, where M is molybd...
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Article
Silica-alumina based nickel-molybdenum catalysts for vacuum gas oil hydrocracking aimed at a higher diesel fraction yield
Nickel-molybdenum hydrocracking catalysts based on amorphous silica-aluminas (ASAs) with Si/Al = 0.3–1.5 have been prepared using chemicals and methods available for catalyst plants. The acidic properties of t...
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Article
Textural characteristics of sulphided hydrotreatment catalysts prepared using Co–Mo complex compounds
Sulphided Co–Mo catalysts prepared by supporting (CoL)2[Mo4(C6H5O7)2O11]·xH2O on γ-Al2O3 were studied. Pores with diameters less than 40 Å in the catalysts preliminary dried at 120 °C were observed. The volume of...
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Article
Synthesis of carbon nanostructures on nickel catalysts from liquid hydrocarbons under conventional and microwave heating