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Article
Modern Catalysts and Methods of Nonoxidative Methane Conversion
Modern methods of nonoxidative methane conversion, as well as catalysts used for this process were considered. The mechanisms of the transformation of the methane molecules on zeolite and metal oxide systems (...
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Article
Cotransformations of n-Hexadecane, Hexene-1, and Cyclohexane over Dual-Zeolite Cracking Catalysts
Characteristic features of the conversion of n-hexadecane, hexene-1, cyclohexane, and their mixtures over dual-zeolite catalysts for co-cracking of light and heavy fractions are considered. The maximum yield of o...
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Article
New Data on the Ability of Alumina–Platinum Systems to Catalyze the Methane Aromatization Reaction under Nonoxidizing Conditions
The state and size of the metal on the surface of aluminum oxide and the acidic properties of the support depending on the concentration of supported platinum were studied in this work. The effect of the Pt co...
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Article
Nonoxidative conversion of methane and n-pentane over a platinum/alumina catalyst
Methane adsorption on the Pt–H/Al2O3 and Pt/Al2O3 catalysts begins at Т = 475°C and is accompanied by the appearance of hydrogen in the reaction medium. At a higher temperature is raised to 550°C, the amount of a...
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Article
The thermodynamic characteristics of ferrocene alkyl and acyl derivatives
The heat capacity of iso-butylferrocene C5H5FeC5H4-C4H9-i was measured over the temperature range 7–372 K in an adiabatic vacuum calorimeter. Substance purity and the thermodynamic characteristics of fusion (temp...
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Article
Thermodynamic functions of buthylderivatives of ferrocene
The heat capacity of isobuthanoylferrocene, C5H5FeC5H4-COCH(CH3)2, was measured by low-temperature adiabatic calorimetry. The purity, temperature, and enthalpy of fusion were obtained. The ideal gas thermodynamic...
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Article
Heat capacity and thermodynamic functions of ferrocenemethanol
The heat capacity (C p, m) of ferrocenemethanol (FM) C5H5FeC5H4CH2OH have been measured by the low-temperature adiabatic calorimetry method in the range 6–371 K. The triple point temperatu...
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Article
The temperature dependences of saturated vapor pressures and heat capacities of some perfluoropolyethers
The borling temperatures of perfluoro-2,4,6,9,11,13-hexaoxy-n-tetradecane, perfluoro-2,4,6,8,11,13,15,17-octaoxy-n-octadecane, and perfluoro-2,4,6,8,11,13,15,17,19,21-decaoxy-n-docosane were determined by compara...