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Article
Study of MO2N catalyst activity and stability in CO oxidation
Unsupported molybdenum nitride powder with Sg of 115 m2g−1 (passivated) has been prepared by the temperature-programmed reaction of MoO3 in H2/N2 mixture. It exhibited high catalytic activity in CO oxidation. DTA...
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Article
A simple and mild derivatization method for hydroxyl compounds using condensation agent carbazole-9-N-(2-methyl)-acetyl-benzene-disulfonate and its application for the determination of volatile alcohols from plasma by HPLC with fluorescence detection
A simple and sensitive HPLC method for the determination of hydroxyl compounds including volatile alcohols from spiked plasma, using a fluorescent condensation agent, namely carbazole-9-N-(2-methyl)-acetyl-be...
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Article
Microwave-Assisted Rapid Preparation of Substituted Carbazole-9-acetic and Propionic Acids and their Absorption and Fluorescence Spectra
A rapid one-pot synthesis of substituted carbazole-9-acetic and -propionic acids under microwave irradiation is described. N-Alkylation and hydrolysis was carried out in DMF without catalyst. The absorption and ...
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Article
An improved derivatization method for sensitive determination of fatty acids by high-performance liquid chromatography using 9-(2-hydroxylethyl)-carbazole as derivatization reagent with fluorescence detection
Tagging techniques with reagents used for fluorescent detection for short and long-chain fatty acids using high-performance liquid chromatography are evaluated in terms of the tagging reactions, handing, flexi...
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Article
Determination of biogenic amines by RPHPLC with fluorescent detection after derivatization with 2-(9-carbazole)ethyl chloroformate (CEOC)
The use of 2-(9-carbazole)ethyl chloroformate (CEOC) for pre-column derivatization of biogenic amines (BA) has been tested for the first time. The reagent reacts completely with BA within 3 min at ambient temp...
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Article
Analysis of Five Pharmacologically Active Compounds from Rhodiola for Natural Product Drug Discovery with Capillary Electrophoresis
A rapid capillary electrophoresis method for the separation of five natural pharmacologically active compounds from extracted Rhodiola, namely salidroside, tyrosol, rhodionin, gallic acid and ethyl gallate has be...
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Article
Development of a Sensitive Reagent, 1,2-Benzo-3,4-dihydrocarbazole-9-ethyl-p-toluenesulfonate, for Determination of Bile Acids in Serum by HPLC with Fluorescence Detection, and Identification by Mass Spectrometry with an APCI Source
A pre-column derivatization method with 1,2-benzo-3,4-dihydrocarbazole-9-ethyl-p-toluenesulfonate (BDETS) as labeling reagent followed by high-performance liquid chromatography with fluorescence detection has bee...
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Article
Pre-Column Derivatization of Amines with 1,2-Benzo-3,4-Dihydrocarbazole-9-Isopropyl Chloroformate Followed by LC-Fluorescence and LC-APCI-MS
A pre-column derivatization method for the sensitive determination of amines using the labeling reagent 1,2-benzo-3,4-dihydrocarbazole-9-isopropyl chloroformate (BCIC-Cl) followed by high-performance liquid ch...
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Article
Determination of 30 Free Fatty Acids in Two Famous Tibetan Medicines by HPLC with Fluorescence Detection and Mass Spectrometric Identification
A simple and sensitive high-performance liquid chromatographic (HPLC) method with fluorescence detection and mass spectrometric identification has been developed for analysis of 30 long-chain and short-chain f...
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Article
Study of a new derivatizing reagent that improves the analysis of amino acids by HPLC with fluorescence detection: application to hydrolyzed rape bee pollen
A simple and sensitive method for evaluating the chemical compositions of protein amino acids, including cystine (Cys)2 and tryptophane (Try) has been developed, based on the use of a sensitive labeling reagent 2...
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Article
Mass Spectrometric Identification of Multihydroxy Phenolic Compounds in Tibetan Herbal Medicines
A highly selective and accurate method based on derivatization with dansyl chloride coupled with liquid chromatography–mass spectrometry has been developed for identification of natural pharmacologically activ...
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Article
Determination of Free Fatty Acids in Bryophyte Plants and Soil by HPLC with Fluorescence Detection and Identification by Online MS
A method for the determination of long and short chain free fatty acids (FFAs), using 1-[2-(p-toluenesulfonate)-ethyl]-2-phenylimidazole-[4,5-f]-9,10-phenanthrene (TSPP) as labeling reagent, has been developed. I...
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Article
CE Determination of 2-(9-Carbazole)ethyl Chloroformate-Labeled Oligopeptides
A pre-column derivatization method for sensitive determination of oligopeptides, using the tagging reagent 2-(9-carbazole)ethyl chloroformate (CEOC-Cl) followed by capillary electrophoresis (CE) with diode-arr...
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Article
LC-DAD-ESI-MS Characterization of Carbohydrates Using a New Labeling Reagent
A novel labeling reagent 1-(2-naphthyl)-3-methyl-5-pyrazolone (NMP) coupling to liquid chromatography with electrospray ionization mass spectrometry for the detection of carbohydrates from the derivatized rape...
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Article
10-Ethyl-acridine-2-sulfonyl Chloride: A New Derivatization Agent for Enhancement of Atmospheric Pressure Chemical Ionization of Estrogens in Urine
The extensive metabolism and treatment of low doses of estrone (E1), estradiol (E2) and estriol (E3) in preclinical animal species necessitates a sensitive analytical method to identify or quantify the estroge...
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Article
Determination and Identification of Primary Aliphatic Amines Using 4-(1H-Phenanthro[9,10-d]Imidazol-2-yl)Benzoic Acid as Novel Pre-Column Labeling Reagent by LC with Fluorescence Detection and Atmospheric Pressure Chemical Ionization Mass Spectroscopy
4-(1H-Phenanthro[9,10-d]imidazol-2-yl)benzoic acid (PIBA), a new amine-reactive fluorescent probe was synthesized and used as a pre-column derivatizing reagent for the determination of aliphatic amines from envir...
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Article
LC–ESI–MS Determination of 20 Free Amino Acids in Tibetan Medicine Gentiana dahurica with Pre-Column Fluorescence Derivatization
Concentrations of 20 free amino aicds (FAAs) in a famous Tibetan medicine Gentiana dahurica was first investigated using 1,2-benzo-3,4-dihydrocarbazole-9-ethyl chloroformate (BCEOC) as the pre-column fluorescence...
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Article
Calculation of the hydrogen binding energies of complexes between formamide and adenine-thymine pair
The hydrogen bonding of complexes formed between formamide and adenine-thymine base pair has been completely investigated in the present study. In order to gain deeper insight into structure, charge distributi...
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Article
A sensitive analytical method for the component monosaccharides of the polysaccharides from a Tibetan herb Potentilla anserine L. by capillary zone electrophoresis with UV detector
A rapid and sensitive method was optimized and validated for the separation and quantification of derivatized monosaccharides in polysaccharide from Potentilla anserine L. using 1-naphthyl-3-methyl-5-pyrazolone (...
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Article
2-(5-Benzoacridine)ethyl-p-toluenesulfonate as sensitive reagent for the determination of bile acids by HPLC with fluorescence detection and online atmospheric chemical ionization-mass spectrometric identification
2-(5-Benzoacridine)ethyl-p-toluenesulfonate (BAETS), a dual-sensitive probe, was reacted with bile acids in the presence of K2CO3 catalyst in dimethyl sulfoxide (DMSO) solvent to give BAETS–bile acid derivatives....