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Article
Electrochemical Behavior of (Fe,Ni)Ox-Based Anodes for Solid-Oxide Fuel Cells in Methane-Containing Atmospheres
The work is devoted to investigation of the electrochemical behavior of (Fe,Ni)Ox-based composite anodes in the hydrogen- and methane-containing fuel. Among the studied composites, the optimum electrochemical cha...
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Article
The Mixed Electronic and Ionic Conductivity of Perovskite-Like Ba1 –xSrxFe1 –yTiyO3 – δ and BaTi0.5Fe0.5 –zCezO3 – δ Solid Solutions
The work is focused on the studying of structural peculiarities, electronic and ionic conductivity, and thermomechanical properties of perovskite-like compositions in Ba1 –xSrxFe1 –yTiyO3 – δ and BaTi0.5Fe0.5 –zC...
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Article
Electrical Conductivity, Thermal Expansion and Electrochemical Properties of Perovskites PrBaFe2–xNi x O5 + δ
In order to evaluate applicability of mixed-conducting PrBaFe2–xNi x О5 + δ perovskites for cathodes of solid oxide fuel cells (SOFCs), their crystal structure, thermal and chemi...
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Article
Oxygen Nonstoichiometry and Transport Properties of Mixed-Conducting Ce0.6–xLa0.4Pr x O2–δ
The oxygen nonstoichiometry and electrical conductivity of fluorite-type solid solutions Ce0.6‒xLa0.4Pr x O2–δ (x = 0.1–0.2) were studied in the oxygen partial pressure range 10–...
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Article
Redox Behavior and Transport Properties of Composites Based on (Fe,Ni)3O4 ± δ for Anodes of Solid Oxide Fuel Cells
The Fe–Ni–O system designed for producing bimetal-containing composite anodes of solid oxide fuel cells (SOFCs) was studied. The solubility of nickel in the structure of spinel (Fe,Ni)3O4 ± δ at atmospheric oxyge...
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Article
Transport and Electrochemical Properties of SrFe(Al,Mo)O3–δ
In this work, effects of molybdenum do** on the crystal structure, stability, electrical conductivity, oxygen permeability and thermomechanical properties of Sr(Fe,Al)O3–δ-based perovskites, were studied. The e...
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Article
Electrophysical and thermomechanical properties of perovskites La0.5A0.5Mn0.5Ti0.5O3–δ (A = Ca, Sr, Ba) used as fuel cell anodes: the effect of radius of alkali-earth cation
The effect of the radius of the alkali-earth cation substituted into the A sublattice of La0.5A0.5Mn0.5Ti0.5O3–δ (А = Са, Sr, Ba) perovskites on their stability and transport and thermomechanical properties is co...
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Article
Stability, mixed conductivity, and thermomechanical properties of perovskite materials for fuel cell electrodes based on La0.5A0.5Mn0.5Ti0.5O3–δ, La0.5Ba0.5Ti0.5Fe0.5O3–δ, and (La0.5А0.5)0.95Cr0.5Fe0.5O3–δ (A = Ca, Ba)
For materials based on ferrites and manganites with Са2+ and Ва2+ cations substituted into А sublattice, the functional properties are studied and the prospects as electrode materials for solid-oxide fuel cells a...
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Article
Electrical, electrochemical, and thermomechanical properties of perovskite-type (La1−x Sr x )1−y Mn0.5Ti0.5O3−δ (x = 0.15–0.75, y = 0–0.05)
Strontium additions in (La1−x Sr x )1−y Mn0.5Ti0.5O3−δ (x = 0.15–0.75, y = 0–0.05) having a rhombohedrally distorted perovskite s...
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Article
Electrochemical behavior of membranes of ion-selective electrodes based on complex oxides
Lead-selective film electrodes with solid contact with membranes on the basis of niobates and vanadates of compositions Sr2.75Pb0.25La(VO4)3, Ba3.8Pb0.2Nb2O9, Ba3.5Pb0.5Nb2O9, Pb3NiNb2O9, and Pb2Nb2O7 are constru...