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Article
The Mixed Electronic and Ionic Conductivity of Perovskite-Like Ba1 –xSrxFe1 –yTiyO3 – δ and BaTi0.5Fe0.5 –zCezO3 – δ Solid Solutions
The work is focused on the studying of structural peculiarities, electronic and ionic conductivity, and thermomechanical properties of perovskite-like compositions in Ba1 –xSrxFe1 –yTiyO3 – δ and BaTi0.5Fe0.5 –zC...
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Article
Oxygen permeability of mixed-conducting composite membranes: effects of phase interaction
Composite ceramic membranes, based on selected combinations of ionic conductors ((La0.9Sr0.1)0.98Ga0.8Mg0.2O3-δ—LSGM or Ce0.8Gd0.2O2-δ—CGO) and electronic/mixed conductors (La2Ni0.8Cu0.2O4+δ—LNC, La0.8Sr0.2Fe0.8C...
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Article
Transport and electrocatalytic properties of La0.3Sr0.7Co0.8Ga0.2O3−δ membranes
Incorporation of gallium into the perovskite lattice of La0.3Sr0.7CoO3−δ leads to increasing unit cell volume and to decreasing thermal expansion, total conductivity and oxygen permeability. At 973–1223 K, the ox...
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Article
Mixed conductivity of gadolinium titanate-based pyrochlore ceramics: The grain boundary effects
In order to reveal the role of grain boundaries on the ionic and electronic conduction processes, the transport properties of Gd2−xGaxTi2O7−δ (x=0.10–0.14) pyrochlore ceramics, pure and with SiO2 additions, were ...
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Article
P-Type electronic conduction in CeO2- and LaGaO3-based solid electrolytes
Modifications of the e.m.f. and faradaic efficiency techniques, taking into account electrode polarization in the measuring cells, in combination with the use of electrodes having sufficiently high polarizatio...
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Article
Synthesis, Physicochemical Characterization and Ionic Conductivity of LaGa0.4Mg0.2M0.4O3−δ (M = Cr, Mn, Fe, Co)
Partial electronic and ionic conductivities, crystal structure, thermal expansion and infrared absorption spectra of the perovskite-type series, LaGa0.40Mg0.20M0.40O3−δ (M = Cr, Mn, Fe, and Co), have been studied...
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Article
Ceria-based materials for solid oxide fuel cells
This paper is focused on the comparative analysis of data on electronic and ionic conduction in gadolinia-doped ceria (CGO) ceramics as well as on the electrochemical properties of various oxide electrodes in ...