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Article
Study of the factors affecting the formation of copper–chromium/aluminum oxide compounds with a spinel structure
The effect of the Cr3+/Al3+ ratio on the crystallization temperature of mixed oxide compounds with a spinel structure and their structural features and morphological characteristics have been studied using a comb...
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Article
Study of leaching of sodium aluminosilicate fiberglass materials
The effects of temperature, time, and the composition of the solvent (water, HCl) on the processes of leaching of Na, Al, and Ca from sodium aluminosilicate fiberglass materials and also the physicochemical pr...
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Article
Structure of Zirconia Nanoparticles used for Pillaring of Clay
SAXS and EXAFS were applied to study genesis of polynuclear zirconium hydroxyspecies in pillaring solutions as dependent upon the zirconium concentration, addition of alkaline-earth chlorides and aging. After ...
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Article
Synthesis, electronic state, and particle size stabilization of nanoparticulate [Co(OH)2(H3O) δ + ]δ+
We have synthesized nanoparticulate cobalt(II) hydroxide containing Co2+ in tetrahedral oxygen coordination (Co Td 2+ ), atypi...
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Article
IR spectroscopic study of the basicity of aminated silica gels
The aminated silica gels SiO2/SOCl2/NH3 (I), SiO2/SiCl4/NH3 (II), SiO2/BCl3/NH3 (III), and SiO2/γ-aminopropyltriethoxysilane (SiO2/APTES, IV) have been synthesized. According to DRIFT spectroscopy and chemical an...
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Article
Synthesis of mesoporous complex framework zirconium phosphates via organicinorganic nanocomposites: genesis of structure, adsorption and catalytic properties
This work presents the first results of synthesis of framework binary phosphates of zirconium and transition metal cations (Co, Cu, Ce) via nanocomposites of starting inorganic salts with citric acid and studi...
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Article
Sorption of carbon dioxide by the composite sorbent “potassium carbonate in porous matrix”
Sorption of CO2 in the presence of water vapor by the K2CO3—γ-Al2O3 composite sorbent was studied by IR spectroscopy in situ, X-ray diffraction analysis, and the differentiating dissolution method and reasons for...
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Article
Adsorption of H3PW12O40 by porous carbon materials
Adsorption of H3PW12O40 from water and organic oxygen-containing solvents (AcOH, Me2CO, MeOH) by carbon mesoporous materials, viz., Sibunit and catalytic filamentous carbons (CFC), was studied. The amount of irre...
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Article
Acidity of heteropoly acids with various structures and compositions studied by IR spectroscopy of the pyridinium salts
The acidity on the “proton affinity” scale was determined by IR spectroscopy of the pyridinium salts for nineteen heteropoly acids of nine structural types (including two with the previously unknown structure)...
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Article
The Microstructure and Properties of Framework Zirconium Phosphates Based Nanocomposites-Catalysts of Alkane Isomerization
The structure and surface properties of composites based upon high-surface-area framework zirconium phosphates with supported WO3, MoO3 and Pt nanoparticles were studied by using combination of structural and spe...
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Article
Nanocomposites Based Upon Alumina and Zirconia Pillared Clays Loaded with Transition Metal Cations and Clusters of Precious Metals: Synthesis, Properties and Catalysis of NOx Selective Reduction by Hydrocarbons
Thermally stable alumina and zirconia pillared clays loaded with copper and cobalt cations and silver nanoparticles were synthesized. The structural and surface features of these nanosystems were studied and c...
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Article
High-Surface - Area Framework Zirconium Phosphates as Catalysts of Hexane Isomerization and Dehydroaromatization: Synthesis and Properties
Mechanochemical activation of solid inorganic precursors and sol-gel routes followed by hydrothermal treatment in the presence of surfactants were used to synthesize highly dispersed NZP-type complex zirconium...
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Article
Dispersed Complex Phosphates as Tailored Acid Catalysts: Synthesis and Properties
The relationship between the chemical composition, bulk real structure, surface properties and catalytic activity of dispersed complex framework zirconium phosphates with a NASICON-type structure is considered...
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Article
Reaction of nitrogen oxides with salts of metal-substituted heteropolyanions
We have used IR spectroscopy to study the reaction with NO and NO2 of solid tetramethylammonium and cesium salts of heteropolyanions (HPA) PW11M(L) 0.39 n− [M=...
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Article
Nonempirical quantum chemical calculations of the vibrational spectra of surface methoxyl groups on aluminum and silicon oxides
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Article
Investigation of the structural changes in bayerite during mechanochemical activation
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The mechanochemical activation of bayerite is accompanied by displacement of the hydroxyl units followed by s...
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Article
Factors affecting the stability and selectivity of zeolites in the conversion of methanol to hydrocarbons. Communication 2. Effect of dealuminization
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Thermochemical treatment of Y and ZSM zeolites with silicon tetrachloride vapor leads to the loss, first, of ...
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Article
Comparative investigation of the catalytic properties of crystalline aluminosilicates of various types. I. Investigation of the state of the oh groups and aluminum atoms in a zeolite skeleton
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Thermochemical treatment of type Y zeolites leads to a redistribution of the A1 atoms of the zeolite skeleton...
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Article
A study of the reactions of isooctane on cracking catalysts by a gradient-free method
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A study of the IR absorption spectra for benzonitrile, pyridine, and CCl4 adsorbed on various amorphous and z...
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