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Nanocomposites Based Upon Alumina and Zirconia Pillared Clays Loaded with Transition Metal Cations and Clusters of Precious Metals: Synthesis, Properties and Catalysis of NOx Selective Reduction by Hydrocarbons

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Abstract

Thermally stable alumina and zirconia pillared clays loaded with copper and cobalt cations and silver nanoparticles were synthesized. The structural and surface features of these nanosystems were studied and compared with those of bulk analogs -partially stabilized zirconias and γ-alumina loaded with the same active components. Specificity of the catalytic properties of nanocomposites in the reactions of nitrogen oxides reduction by propane, propylene and decane in the excess of oxygen appears to be determined both by the degree of interaction between pillars and active components and the type of reducing agent.

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Authors and Affiliations

  1. Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Lavrentieva, 5, Novosibirsk, Russia, 630090

    Vladislav A. Sadykov, R. V. Bunina, G. M. Alikina, V. P. Doronin, T. P. Sorokina, D. I. Kochubei, B. N. Novgorodov, E. A. Paukshtis, V. B. Fenelonov, A. Yu. Derevyankin, A. S. Ivanova, V. I. Zaikovskii, T. G. Kuznetsova, V. N. Kolomiichuk & L. M. Plasova

  2. Novosibirsk State University, Pirogova, 1, Novosibirsk, Russia, 630090

    Vladislav A. Sadykov & B. A. Beloshapkin

  3. Semenov Institute of Chemical Physics RAS, Moscow, Russia

    V. A. Matyshak & G. A. Konin

  4. Topchiev Institute of Petrochemical Synthesis RAS, Moscow, Russia

    A. Ya. Rozovskii, V. F. Tretyakov, T. N. Burdeynaya & M. N. Davydova

  5. University of Limerick, Limerick, Ireland

    J. R. H. Ross, J. P. Breen & F. C. Meunier

Authors
  1. Vladislav A. Sadykov
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  2. R. V. Bunina
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  3. G. M. Alikina
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  4. V. P. Doronin
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  5. T. P. Sorokina
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  6. D. I. Kochubei
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  7. B. N. Novgorodov
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  8. E. A. Paukshtis
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  9. V. B. Fenelonov
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  10. A. Yu. Derevyankin
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  11. A. S. Ivanova
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  12. V. I. Zaikovskii
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  13. T. G. Kuznetsova
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  14. B. A. Beloshapkin
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  15. V. N. Kolomiichuk
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  16. L. M. Plasova
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  17. V. A. Matyshak
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  18. G. A. Konin
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  19. A. Ya. Rozovskii
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  20. V. F. Tretyakov
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  21. T. N. Burdeynaya
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  22. M. N. Davydova
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  23. J. R. H. Ross
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  24. J. P. Breen
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  25. F. C. Meunier
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Corresponding author

Correspondence to Vladislav A. Sadykov.

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Sadykov, V.A., Bunina, R.V., Alikina, G.M. et al. Nanocomposites Based Upon Alumina and Zirconia Pillared Clays Loaded with Transition Metal Cations and Clusters of Precious Metals: Synthesis, Properties and Catalysis of NOx Selective Reduction by Hydrocarbons. MRS Online Proceedings Library 581, 435–440 (1999). https://doi.org/10.1557/PROC-581-435

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  • DOI: https://doi.org/10.1557/PROC-581-435

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