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  1. No Access

    Article

    Selective oxidation of hydrocarbons into synthesis gas at short contact times: Design of monolith catalysts and main process parameters

    This review summarizes the main achievements of the Boreskov Institute of Catalysis (Siberian Division, Russian Academy of Sciences) in the development of efficient and stable monolith catalysts for selective ...

    V. A. Sadykov, S. N. Pavlova, R. V. Bunina, G. M. Alikina… in Kinetics and Catalysis (2005)

  2. No Access

    Article

    Molecular design and characterization of catalysts for NO x selective reduction by hydrocarbons in the oxygen excess based upon ultramicroporous zirconia pillared clays

    Approaches to design of zirconia pillared clays via control of the properties of pillaring species in solutions were elaborated. Structural features of pillars and Pt + Cu active components fixed at these nano...

    V. A. Sadykov, T. G. Kuznetsova, V. P. Doronin, E. M. Moroz… in Topics in Catalysis (2005)

  3. No Access

    Article

    Synthesis of mesoporous complex framework zirconium phosphates via organicinorganic nanocomposites: genesis of structure, adsorption and catalytic properties

    This work presents the first results of synthesis of framework binary phosphates of zirconium and transition metal cations (Co, Cu, Ce) via nanocomposites of starting inorganic salts with citric acid and studi...

    Yulia V. Frolova, Vladislav A. Sadykov, S. N. Pavlova… in MRS Online Proceedings Library (2004)

  4. No Access

    Article

    Cu, Co, Ag-Containing Pillared Clays as Catalysts for the Selective Reduction of NOx by Hydrocarbons in an Excess of Oxygen

    Thermally stable Al- and Zr-PILC loaded with copper and cobalt cations and silver nanoparticles were synthesized. The structural and surface features of these nanosystems were studied and compared with those o...

    G.A. Konin, A.N. Il'ichev, V.A. Matyshak, T.I. Khomenko… in Topics in Catalysis (2001)

  5. No Access

    Article

    Nanocomposites Based Upon Alumina and Zirconia Pillared Clays Loaded with Transition Metal Cations and Clusters of Precious Metals: Synthesis, Properties and Catalysis of NOx Selective Reduction by Hydrocarbons

    Thermally stable alumina and zirconia pillared clays loaded with copper and cobalt cations and silver nanoparticles were synthesized. The structural and surface features of these nanosystems were studied and c...

    Vladislav A. Sadykov, R. V. Bunina, G. M. Alikina… in MRS Online Proceedings Library (1999)

  6. No Access

    Article

    Reactivity and transformation routes of surface nitrates in the reaction of NOx reduction by C3H8 over cation-exchanged zeolites

    FITRS combined with15N and18O isotope substitution and TPD have revealed that nitrates are the most abundant ad-NOx species on over-exchanged Cu- and Co-ZSM-5 zeolites. the transformation rates of such species un...

    V. A. Sadykov, E. A. Paukshtis… in Reaction Kinetics and Catalysis Letters (1998)

  7. No Access

    Article

    Hydrocarbon specificity in the selective catalytic reduction of NOx over Cu-ZSM-5 and Co-ZSM-5 catalysts

    Transformation of surface nitrates under CH4 (CH4+O2) was found to ensure steady-state activity of Co-ZSM-5 in the selective catalytic reduction of nitrogen oxides by methane (CH4-SCR). For Cu-ZSM-5, such species...

    V. A. Sadykov, S. A. Beloshapkin… in Reaction Kinetics and Catalysis Letters (1998)

  8. No Access

    Article

    A role of surface nitrite and nitrate complexes in NOx selective catalytic reduction by hydrocarbons under oxygen excess

    NO adsorption over three types of catalytic systems, such as cation-exchanged zeolites, transition metal oxides supported on γ-Al2O3, and partially stabilised tetragonal ZrO2 (PSZ) was studied by using the TPD me...

    V. A. Sadykov, S. L. Baron, V. A. Matyshak, G. M. Alikina… in Catalysis Letters (1996)

  9. No Access

    Article

    Mechanism of carbon monoxide oxidation on nickel oxide and its solid solutions

    On the basis of studying the isotope exchange of oxygen and the position of the Fermi level in the system MiO−LixNi1−xO, an explanation is proposed for the compensation effect in the reaction of CO oxidation on n...

    N. P. Keyer, G. L. Semin, R. V. Bunina in Reaction Kinetics and Catalysis Letters (1977)

  10. No Access

    Article

    NO adsorption on tin(IV) oxide

    The adsorption of NO on SnO2 has been studied in the temperature range from 0 to 86°C, at pressures from 0.4 to 3.5 Torr. The adsorption isotherms are described by the Freundlich equation. The rate of adsorption ...

    R. V. Bunina, I. S. Sazonova, N. P. Keier… in Reaction Kinetics and Catalysis Letters (1976)

  11. No Access

    Article

    Determination of surface nickel concentration on solid solutions of MgO−NiO by the selective chemisorption of NO

    The concentration of nickel cations on the surface of MgO−NiO solid solutions was determined by the method of selective NO chemisorption. Their concentration was found to be equal to the bulk concentration det...

    R. V. Bunina, I. S. Sazonova in Reaction Kinetics and Catalysis Letters (1975)