Log in

Cu5Zn8 Growth Reversion in Cu/Sn-8Zn-3Bi/Cu During Discontinuous Electromigration

  • Published:
Journal of Electronic Materials Aims and scope Submit manuscript

Abstract

A Cu/Sn-8Zn-3Bi/Cu structure was used to investigate the intermetallic compound (IMC) growth behavior during discontinuous electromigration under current density of 104 A/cm2 at 70°C. Cu5Zn8 IMC formed at both the anode and the cathode interfaces, and the thickness increased with the stressing time. With prolonging the current stressing time, a bulged Cu5Zn8 layer was squeezed out between the former Cu5Zn8 layer and Cu substrate in the samples to relax the excess compressive stress. Additionally, due to the back stress gradient built up by the Sn diffusion, the Zn atomic flux reacted with Cu to form Cu5Zn8 at the cathode side when the power was turned off. Finally, the total IMC thickness of the anode and the cathode under discontinuous current stressing showed a “reversion” in the 69 h and 310 h samples.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Subscribe and save

Springer+ Basic
EUR 32.99 /Month
  • Get 10 units per month
  • Download Article/Chapter or Ebook
  • 1 Unit = 1 Article or 1 Chapter
  • Cancel anytime
Subscribe now

Buy Now

Price includes VAT (Germany)

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. C.M.L. Wu, D.Q. Yu, C.M.T. Law, and L. Wang, Mater. Sci. Eng. R 44, 1 (2004).

    Article  Google Scholar 

  2. S.W. Kim, J.W. Yoon, and S.B. Jung, J. Electron. Mater. 33, 1182 (2004).

    Article  CAS  Google Scholar 

  3. K.L. Chen, S.C. Cheng, S. Wu, and K.L. Lin, J. Alloy. Compd. 416, 98 (2006).

    Article  CAS  Google Scholar 

  4. C.T. Lin, C.S. Hsi, M.C. Wang, T.C. Chang, and M.K. Liang, J. Alloy. Compd. 459, 225 (2008).

    Article  CAS  Google Scholar 

  5. K.W. Lin, L.H. Wen, and T.P. Liu, J. Electron. Mater. 27, 97 (1998).

    Article  CAS  Google Scholar 

  6. S.W. Liang, H.Y. Hsiao, C. Chen, L.H. Xu, K.N. Tu, and Y.S. Lai, J. Electron. Mater. 38, 2443 (2009).

    Article  CAS  Google Scholar 

  7. S.S. Ha, J.W. Kim, J.W. Yoon, S.O. Ha, and S.B. Jung, J. Electron. Mater. 38, 70 (2009).

    Article  CAS  Google Scholar 

  8. R. Othman, D.N. Binh, A.B. Ismail, B.D. Long, and T. Ariga, Intermetallics 22, 1 (2012).

    Article  CAS  Google Scholar 

  9. L.M. Ma, F. Guo, G.C. Xu, X.T. Wang, H.W. He, and H.Y. Zhao, J. Electron. Mater. 41, 425 (2012).

    Article  CAS  Google Scholar 

  10. J.M. Kim, M.H. Jeong, S. Yoo, and Y.B. Park, J. Electron. Mater. 41, 791 (2012).

    Article  CAS  Google Scholar 

  11. W.H. Lin, A.T. Wu, S.Z. Lin, and K.N. Tu, J. Electron. Mater. 36, 753 (2007).

    Article  CAS  Google Scholar 

  12. C.M. Chen, Y.M. Hung, and C.H. Lin, J. Alloy. Compd. 475, 238 (2009).

    Article  CAS  Google Scholar 

  13. L.J. Liu, W. Zhou, H.B. Zhang, B.L. Li, and P. Wu, Microelectron. Reliab. 50, 251 (2010).

    Article  CAS  Google Scholar 

  14. X. Gu, K.C. Yung, Y.C. Chan, and D. Yang, J. Mater. Sci.: Mater. Electron. 22, 217 (2011).

    Article  CAS  Google Scholar 

  15. L.J. Liu, W. Zhou, B.L. Li, and P. Wu, Mater. Chem. Phys. 123, 629 (2010).

    Article  CAS  Google Scholar 

  16. C.F. Yang, S.W. Chen, K.H. Wu, and T.S. Chin, J. Electron. Mater. 36, 1524 (2007).

    Article  CAS  Google Scholar 

  17. C.Y. Chou and S.W. Chen, Acta Mater. 54, 2393 (2006).

    Article  CAS  Google Scholar 

  18. S.M. Kuo and K.L. Lin, J. Electron. Mater. 37, 1611 (2008).

    Article  CAS  Google Scholar 

  19. K.L. Lin, P.C. Liu, and J.M. Song, IEEE Electronic Components and Technology Conference (2004), p. 1310.

  20. R. Hultgren, P.D. Desai, D.T. Hawkins, M. Gleiser, and K.K. Kelley, Selected Values of the Thermodynamic Properties of Binary Alloys (Metals Park, OH: American Society for Metals, 1973).

  21. X.F. Zhang and J.D. Guo, Scr. Mater. 57, 513 (2007).

    Article  CAS  Google Scholar 

  22. A.D. Smigelkas and E.O. Kirkrndall, Trans. AIME 130, 171 (1947).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to ** Wu.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Liu, J., Zhou, W., Liu, L. et al. Cu5Zn8 Growth Reversion in Cu/Sn-8Zn-3Bi/Cu During Discontinuous Electromigration. J. Electron. Mater. 41, 2045–2050 (2012). https://doi.org/10.1007/s11664-012-2131-5

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11664-012-2131-5

Keywords

Navigation