Abstract
A Cu/Sn-8Zn-3Bi/Cu structure was used to investigate the intermetallic compound (IMC) growth behavior during discontinuous electromigration under current density of 104 A/cm2 at 70°C. Cu5Zn8 IMC formed at both the anode and the cathode interfaces, and the thickness increased with the stressing time. With prolonging the current stressing time, a bulged Cu5Zn8 layer was squeezed out between the former Cu5Zn8 layer and Cu substrate in the samples to relax the excess compressive stress. Additionally, due to the back stress gradient built up by the Sn diffusion, the Zn atomic flux reacted with Cu to form Cu5Zn8 at the cathode side when the power was turned off. Finally, the total IMC thickness of the anode and the cathode under discontinuous current stressing showed a “reversion” in the 69 h and 310 h samples.
Similar content being viewed by others
References
C.M.L. Wu, D.Q. Yu, C.M.T. Law, and L. Wang, Mater. Sci. Eng. R 44, 1 (2004).
S.W. Kim, J.W. Yoon, and S.B. Jung, J. Electron. Mater. 33, 1182 (2004).
K.L. Chen, S.C. Cheng, S. Wu, and K.L. Lin, J. Alloy. Compd. 416, 98 (2006).
C.T. Lin, C.S. Hsi, M.C. Wang, T.C. Chang, and M.K. Liang, J. Alloy. Compd. 459, 225 (2008).
K.W. Lin, L.H. Wen, and T.P. Liu, J. Electron. Mater. 27, 97 (1998).
S.W. Liang, H.Y. Hsiao, C. Chen, L.H. Xu, K.N. Tu, and Y.S. Lai, J. Electron. Mater. 38, 2443 (2009).
S.S. Ha, J.W. Kim, J.W. Yoon, S.O. Ha, and S.B. Jung, J. Electron. Mater. 38, 70 (2009).
R. Othman, D.N. Binh, A.B. Ismail, B.D. Long, and T. Ariga, Intermetallics 22, 1 (2012).
L.M. Ma, F. Guo, G.C. Xu, X.T. Wang, H.W. He, and H.Y. Zhao, J. Electron. Mater. 41, 425 (2012).
J.M. Kim, M.H. Jeong, S. Yoo, and Y.B. Park, J. Electron. Mater. 41, 791 (2012).
W.H. Lin, A.T. Wu, S.Z. Lin, and K.N. Tu, J. Electron. Mater. 36, 753 (2007).
C.M. Chen, Y.M. Hung, and C.H. Lin, J. Alloy. Compd. 475, 238 (2009).
L.J. Liu, W. Zhou, H.B. Zhang, B.L. Li, and P. Wu, Microelectron. Reliab. 50, 251 (2010).
X. Gu, K.C. Yung, Y.C. Chan, and D. Yang, J. Mater. Sci.: Mater. Electron. 22, 217 (2011).
L.J. Liu, W. Zhou, B.L. Li, and P. Wu, Mater. Chem. Phys. 123, 629 (2010).
C.F. Yang, S.W. Chen, K.H. Wu, and T.S. Chin, J. Electron. Mater. 36, 1524 (2007).
C.Y. Chou and S.W. Chen, Acta Mater. 54, 2393 (2006).
S.M. Kuo and K.L. Lin, J. Electron. Mater. 37, 1611 (2008).
K.L. Lin, P.C. Liu, and J.M. Song, IEEE Electronic Components and Technology Conference (2004), p. 1310.
R. Hultgren, P.D. Desai, D.T. Hawkins, M. Gleiser, and K.K. Kelley, Selected Values of the Thermodynamic Properties of Binary Alloys (Metals Park, OH: American Society for Metals, 1973).
X.F. Zhang and J.D. Guo, Scr. Mater. 57, 513 (2007).
A.D. Smigelkas and E.O. Kirkrndall, Trans. AIME 130, 171 (1947).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Liu, J., Zhou, W., Liu, L. et al. Cu5Zn8 Growth Reversion in Cu/Sn-8Zn-3Bi/Cu During Discontinuous Electromigration. J. Electron. Mater. 41, 2045–2050 (2012). https://doi.org/10.1007/s11664-012-2131-5
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11664-012-2131-5