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Organic Brønsted Acid-Catalyzed Stereoselective Cationic RAFT Polymerization: The Effect of RAFT Agents
The tacticity of vinyl polymers is a key factor affecting the properties of materials. Recently, organic Brønsted acids have been demonstrated as...
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Synthesis of Poly(styrene)-g-Poly(oleic acid) Graft Copolymers via Reversible Addition/Fragmentation Transfer (RAFT) Polymerization Using a Poly Oleic Acid Macro-RAFT Agent
In this study, a new polymeric oleic acid-derived macro addition/fragmentation transfer agent was utilized to produce a poly(styrene)- g -poly(oleic...
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Study on two different dithiobenzoates effectiveness in bulk RAFT polymerization of β-myrcene
The study aimed to evaluate the impact of two chain transfer controllers, ethyl 2-(phenylcarbonothiolthio)-2-phenylacetate (EPPA) and...
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RAFT agent effect on graft poly(acrylic acid) to polypropylene glycol fumarate phthalate
Understanding the physical and chemical properties of new-generation polymeric materials during the synthesis is very important in obtaining the...
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Efficient synthesis of bottle-brush polymers enabled by selective photoactivation strategy in NIR-induced PET-RAFT polymerization
Bottle-brush polymers possessing densely grafted side chains have special properties that are distinct from linear macromolecules. Herein, an...
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Double hydrophilic thermo-sensitive macro-RAFT agents as stabilizers and control agents in styrene emulsion polymerization
The properties of amphiphilic triblock copolymer particles, which consist of a hydrophobic polystyrene (PS) core and a thermo-sensitive double...
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RAFT Dispersion Polymerization of Nitrobenzene-based Monomer and Photo-response of its Polymer Nanoparticles
The poly[ N,N -(dimethylamino) ethyl methacrylate] (PDMAEMA) macro-RAFT agent mediated dispersion polymerization of photo-responsive nitrobenzene-based...
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Persistent radical anion of perylene dianhydride: an emerging metal-free photocatalyst for near-infrared photocontrolled RAFT polymerization
Develo** a new type of photocatalyst (PC) and catalytic mechanism for near-infrared (NIR) photocontrolled reversible-deactivation radical...
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Synthesis of functional fluorinated copolymers with different microstructure via reversible addition-fragmentation chain transfer (RAFT) process
Fluoropolymers are attractive due to their high resistance to external influences. However, they are poorly compatible with other materials (for...
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Synthesis and characterization of a brush type graft copolymer via RAFT and "click" chemistry methods
In this study, well-known poly(4-vinylbenzyl- g -ethylene glycol) [P(4-VB- g -EG)] brush type graft copolymer was synthesized by recycling...
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RAFT polymerization of MMA in channels of different mesoporous materials
A series of mesoporous silica (MS) materials, including rod-like and spherical SBA-15, spherical MCM-41, and MCM-48, was successfully synthesized and...
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Preparation and Application of Nitrobenzene-Containing Copolymer Nanoparticles Obtained by RAFT Dispersion Polymerization
In this study, the photoresponsive monomer of 2-nitrobenzyl methacrylate (NBMA) was introduced into the dispersion polymerization of benzyl...
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Conventional Radical and RAFT Alternating Copolymerizations of Hydroxyalkyl Vinyl Ethers and Dialkyl Maleates
The alternating copolymerization of hydroxyalkyl vinyl ethers and dialkyl maleates is investigated by conventional radical polymerization and...
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Synthesis and characterization of poly(epichlorohydrin-g-4-vinylbenzyl-g-methyl methacrylate) graft copolymer by combination of ROP, RAFT, and ATRP Technics
Synthesis of poly(epichlorohydrin-g-4-vinylbenzyl-g-methyl methacrylate) [poly(ECH-g-VB-g-MMA)] graft copolymer was carried out by cationic...
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Dual-responsive polymers synthesized via RAFT polymerization for controlled demulsification and desorption
Intelligent polymers responsive to the environment have aroused widespread interest in many applications of materials and interfaces. However,...
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Poly(ethyl methacrylate)-based diblock copolymer nano-objects prepared via RAFT-mediated polymerization induced self-assembly in n-heptane
A series of poly(lauryl methacrylate)-poly(ethyl methacrylate) (PLMA-PEMA) diblock copolymer nano-objects were prepared via reversible...
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RAFT-mediated polymerization-induced self-assembly of cholic acid-derived monomer
This contribution used polymerization-induced self-assembly (PISA) to prepare PHEA- b -PCAE block copolymers that self-assemble simultaneously, forming...
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Peculiarities of reversible addition-fragmentation chain transfer (RAFT) polymerization in the presence of switchable RAFT agent
This article dwells on the issues of investigating 1-cyano-1-methylethylmethyl(4-pyridinyl)dithiocarbamate in reversible addition-fragmentation chain...
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Preparation of PNIPAM-Azo by RAFT polymerization and their application in thermo- and light-responsive hydrogel
Thermo-responsive poly( N -isopropylacrylamide) with terminal azobenzene group (PNIPAM-Azo) can show distinct property changes in response to...
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pH-responsive amphiphilic copolymers based on N-vinylpyrrolidone and fluoroacrylates with different structures: synthesis via RAFT process and surface properties
The copolymerization of 1,1,1,3,3,3-hexafluoroisopropylacrylate (HFIPA) and 2,2,3,3,4,4,5,5-octafluoropentyl acrylate (OFPA) with N-vinylpyrrolidone...
