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Open AccessDMT1-dependent endosome-mitochondria interactions regulate mitochondrial iron translocation and metastatic outgrowth
Transient early endosome (EE)-mitochondria interactions can mediate mitochondrial iron translocation, but the associated mechanisms are still elusive. We showed that Divalent Metal Transporter 1 (DMT1) sustain...
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Article
Open AccessExpression of hypoxia-inducible genes is suppressed in altered gravity due to impaired nuclear HIF1α accumulation
Extravehicular activities, the backbone of manned space exploration programs, set astronauts into mild hypoxia. Unfortunately, microgravity aggravates threatening symptoms of hypoxia such as vision impairment ...
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Article
Mechanism of mediated alkali peroxide oxidation and triplet versus singlet oxygen formation
Aprotic alkali metal–O2 batteries face two major obstacles to their chemistry occurring efficiently, the insulating nature of the formed alkali superoxides/peroxides and parasitic reactions that are caused by the...
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Article
Everlasting rhodamine dyes and true deciding factors in their STED microscopy performance
The authors took an independent and closer look at the family of red-emitting rhodamine dyes known for a decade due to their excellent performance in STED microscopy. After the family was further extended, the...
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Article
Open AccessCorrection to: Use of an oxygen planar optode to assess the effect of high velocity microsprays on oxygen penetration in a human dental biofilms in-vitro
An amendment to this paper has been published and can be accessed via the original article.
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Article
Open AccessUse of an oxygen planar optode to assess the effect of high velocity microsprays on oxygen penetration in a human dental biofilms in-vitro
Dental plaque biofilms are the causative agents of caries, gingivitis and periodontitis. Both mechanical and chemical strategies are used in routine oral hygiene strategies to reduce plaque build-up. If allowe...
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Article
Open AccessIridium Corroles Exhibit Weak Near-Infrared Phosphorescence but Efficiently Sensitize Singlet Oxygen Formation
Six-coordinate iridium(III) triarylcorrole derivatives, Ir[TpXPC)]L2, where TpXPC = tris(para-X-phenyl)corrole (X = CF3, H, Me, and OCH3) and L = pyridine (py), trimethylamine (tma), isoquinoline (isoq), 4-dimeth...
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Article
Ambient-temperature near-IR phosphorescence and potential applications of rhenium-oxo corroles
Presented herein is a first photophysical investigation of a series of rhenium(V)-oxo tris(p-X-phenyl)corroles, Re[TpXPC](O), where X = CF3, F, H, CH3, and OCH3. The complexes all exhibit near-IR phosphorescence ...
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Article
Open AccessDeactivation of redox mediators in lithium-oxygen batteries by singlet oxygen
Non-aqueous lithium-oxygen batteries cycle by forming lithium peroxide during discharge and oxidizing it during recharge. The significant problem of oxidizing the solid insulating lithium peroxide can greatly ...
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Article
Open AccessAirway surface liquid pH is not acidic in children with cystic fibrosis
Modulation of airway surface liquid (ASL) pH has been proposed as a therapy for cystic fibrosis (CF). However, evidence that ASL pH is reduced in CF is limited and conflicting. The technical challenges associa...
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Article
Singlet oxygen generation as a major cause for parasitic reactions during cycling of aprotic lithium–oxygen batteries
Non-aqueous metal–oxygen batteries depend critically on the reversible formation/decomposition of metal oxides on cycling. Irreversible parasitic reactions cause poor rechargeability, efficiency, and cycle lif...
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Article
In-line monitoring of pH and oxygen during enzymatic reactions in off-the-shelf all-glass microreactors using integrated luminescent microsensors
We describe a maskless photopolymerization technique for integration of luminescent sensors for determination of pH values and dissolved oxygen (DO) into commercially available all-glass microfluidic reactors ...
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Article
Imaging oxygen in neural cell and tissue models by means of anionic cell-permeable phosphorescent nanoparticles
Cell-permeable phosphorescent probes enable the study of cell and tissue oxygenation, bioenergetics, metabolism, and pathological states such as stroke and hypoxia. A number of such probes have been described ...
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Article
Ultra-sensitive optical oxygen sensors for characterization of nearly anoxic systems
Oxygen quantification in trace amounts is essential in many fields of science and technology. Optical oxygen sensors proved invaluable tools for oxygen measurements in a broad concentration range, but until no...
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Indicators for optical oxygen sensors
Continuous monitoring of oxygen concentration is of great importance in many different areas of research which range from medical applications to food packaging. In the last three decades, significant progress...
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Article
New luminescent oxygen-sensing and temperature-sensing materials based on gadolinium(III) and europium(III) complexes embedded in an acridone–polystyrene conjugate
New sensing materials have been developed which rely on the use of luminescent europium(III) and gadolinium(III) complexes with thenoylacetylacetonate embedded in an acridone–polystyrene conjugate. Acridone ac...
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Article
Open AccessIndicators for optical oxygen sensors
Continuous monitoring of oxygen concentration is of great importance in many different areas of research which range from medical applications to food packaging. In the last three decades, significant progress...
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Article
Open AccessErratum to: A novel planar optical sensor for simultaneous monitoring of oxygen, carbon dioxide, pH and temperature
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Article
Open AccessNew fluorescent perylene bisimide indicators—a platform for broadband pH optodes
Asymmetric perylene bisimide (PBI) dyes are prepared and are shown to be suitable for the preparation of fluorescence chemosensors for pH. They carry one amino-functional substituent which introduces pH sensit...
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Article
Open AccessA novel planar optical sensor for simultaneous monitoring of oxygen, carbon dioxide, pH and temperature
The first quadruple luminescent sensor is presented which enables simultaneous detection of three chemical parameters and temperature. A multi-layer material is realized and combines two spectrally independent...