5 Result(s)
within
Miquel Costas
Science, Humanities and Social Sciences, multidisciplinary
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Article
Open AccessCharacterized cis-FeV(O)(OH) intermediate mimics enzymatic oxidations in the gas phase
FeV(O)(OH) species have long been proposed to play a key role in a wide range of biomimetic and enzymatic oxidations, including as intermediates in arene dihydroxylation catalyzed by Rieske oxygenases. However, t...
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Article
Erratum: Evidence for an oxygen evolving iron–oxo–cerium intermediate in iron-catalysed water oxidation
Nature Communications 6: Article number:5865 (2015); Published 22 January 2015; Updated 12 February 2015. The affiliation details for Laura Gómez, Scott T. Kleespies and Lawrence Que Jr are incorrect in this A...
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Article
Evidence for an oxygen evolving iron–oxo–cerium intermediate in iron-catalysed water oxidation
The non-haem iron complex α-[FeII(CF3SO3)2(mcp)] (mcp=(N,N′-dimethyl-N,N′-bis(2-pyridylmethyl)-1,2-cis-diaminocyclohexane) reacts with CeIV to oxidize water to O2, representing an iron-based functional model for ...
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Article
Sponge-like molecular cage for purification of fullerenes
Since fullerenes are available in macroscopic quantities from fullerene soot, large efforts have been geared toward designing efficient strategies to obtain highly pure fullerenes, which can be subsequently ap...
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Article
Direct observation of two-electron Ag(I)/Ag(III) redox cycles in coupling catalysis
Silver is extensively used in homogeneous catalysis for organic synthesis owing to its Lewis acidity, and as a powerful one-electron oxidant. However, two-electron redox catalytic cycles, which are most common...
