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Article
Oxoiron(IV) complexes as synthons for the assembly of heterobimetallic centers such as the Fe/Mn active site of Class Ic ribonucleotide reductases
Nonheme oxoiron(IV) complexes can serve as synthons for generating heterobimetallic oxo-bridged dimetal complexes by reaction with divalent metal complexes. The formation of FeIII–O–CrIII and FeIII–O–MnIII comple...
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Article
Erratum: Evidence for an oxygen evolving iron–oxo–cerium intermediate in iron-catalysed water oxidation
Nature Communications 6: Article number:5865 (2015); Published 22 January 2015; Updated 12 February 2015. The affiliation details for Laura Gómez, Scott T. Kleespies and Lawrence Que Jr are incorrect in this A...
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Article
Evidence for an oxygen evolving iron–oxo–cerium intermediate in iron-catalysed water oxidation
The non-haem iron complex α-[FeII(CF3SO3)2(mcp)] (mcp=(N,N′-dimethyl-N,N′-bis(2-pyridylmethyl)-1,2-cis-diaminocyclohexane) reacts with CeIV to oxidize water to O2, representing an iron-based functional model for ...