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  1. Article

    Open Access

    Chemoselectivity in the Oxidation of Cycloalkenes with a Non-Heme Iron(IV)-Oxo-Chloride Complex: Epoxidation vs. Hydroxylation Selectivity

    We report and analyze chemoselectivity in the gas phase reactions of cycloalkenes (cyclohexene, cycloheptene, cis-cyclooctene, 1,4-cyclohexadiene) with a non-heme iron(IV)-oxo complex [(PyTACN)Fe(O)(Cl)]+, which ...

    Thibault Terencio, Erik Andris, Ilaria Gamba… in Journal of The American Society for Mass S… (2019)

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  2. Article

    Open Access

    Characterized cis-FeV(O)(OH) intermediate mimics enzymatic oxidations in the gas phase

    FeV(O)(OH) species have long been proposed to play a key role in a wide range of biomimetic and enzymatic oxidations, including as intermediates in arene dihydroxylation catalyzed by Rieske oxygenases. However, t...

    Margarida Borrell, Erik Andris, Rafael Navrátil, Jana Roithová… in Nature Communications (2019)

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