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Article
Grafted Poly(acrylic acid) Brushes for Cell-Surface Interactions
Poly(acrylic acid) (PAA) was grafted onto RF plasma treated PET films and onto SiO2 covered glass surfaces. PET films with various amounts of grafted PAA (0.4, 5, 11 and 19 μm/cm2) were immersed into a solution o...
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Chapter
Porous Organosilicates for On-Chip Applications: Dielectric Generational Extendibility by the Introduction of Porosity
Dense alkyl-functionalized organosilicates have dielectric constants that are 25-30% lower than silica, which allows ultralow dielectric targets(κ< 2.2) to be achieved at reduced porosity levels relative to those...
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Article
Structural properties of star-like dendrimers in solution
We measured the form factor of star-like poly-ε-caprolactone dendrimers under good solvent conditions with small-angle neutron scattering (SANS). The parameters varied in the experiment were the dendrimer gene...
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Article
Porous Organosilicates for On-Chip Dielectric Applications
Porous organosilicates useful for on-chip insulator applications can be prepared by templating the vitrification of low molecular weight silsesquioxanes (SSQs) using highly branched, thermally labile macromole...
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Book
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Chapter
Nanoporous Polyimides
Foamed polyimides have been developed in order to obtain thin film dielectric layers with very low dielectric constants for use in microelectronic devices. In these systems the pore sizes are in the nanometer ...
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Article
Phase-Separated Inorganic-Organic Hybrids for Microelectronic Applications
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Article
Toughened, Inorganic-Organic Hybrid Materials for Microelectronic Application
Transparent, nanophase-separated, inorganic-organic hybrid polymers with dielectric constants below 3.0 have been prepared from reactively functionalized poly(amic ester) derivatives and substituted, oligomeri...
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Article
Nanoporous Polyimide Films from Polyimide-Aliphatic Polyester or Polyimide-Aliphatic Polycarbonate Copolymers
We have explored polyimide foams created using a block copolymer approach as part of our research efforts to obtain thin film dielectric layers with very low dielectric constants for use in microelectronic dev...
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Article
Macroporous Thermosets Via Chemically Induced Phase Separation
We have explored a new technology based on chemically induced phase separation that yields porous epoxies and cyanurates with a closed cell morphology and micrometer sized pores with a narrow pore size distrib...
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Article
Foamed Elastomers for Packaging Interconnections, Testing and Burn-In Applications
The present study is directed to a new foamed elastomer composition for supporting the interconnecting conductive wires in the Elasticon™ interposer connector for the packaging interconnections, test and burn-...
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Article
Characterization of thin Polymeric Nanofoam films by Transmission Electron Microscopy and Small Angle Neutron Scattering
Thin film polymer nanofoams are produced from triblock copolymers of a fluorinated polyimide, 3F/PMDA (derived from pyromelletic dianhydride (PMDA) and 1,1-bis(4-aminophenyl)-1-phenyl-2,2,2-trifluoroethane (3F...
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Article
Microporous Crosslinked Elastomers
Elastomeric connectors have been developed for a wide variety of interconnection and test applications which include module-to-board, board-to-board interconnections, high density module, board and LCD testing...
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Article
Nanofoam Porosity Measured by Infrared Spectroscopy and Refractive Index
Infrared spectroscopy and optical waveguide were used to determine the porosity of polymer nanofoams produced from block copolymers of an aromatic polyimide endcapped with either poly(propyIene oxide) or poly(...
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Article
Polyimide Nanofoams For Low Dielectric Applications
Foamed polyimides have been developed in order to obtain thin film dielectric layers with very low dielectric constants for use in microelectronic devices. In these systems the pore sizes are in the nanometer ...
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Article
High Temperature Polyimide Nanofoams
A means of generating high temperature polymer foams which leads to pore size in the nanometer regime has been developed. Nanofoams were prepared by casting block copolymers comprised of a thermally stable blo...
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Article
A method for rubber toughening powder coatings
This paper describes a new method for rubber toughening brittle powder coatings. The design involves the use of toughening agents with specific physical and chemical properties. The modifiers are low-to-medium...
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Article
Progress on Nonlinear Optical Chromophores and Polymers with Useful Nonlinearity and Thermal Stability
Organic nonlinear optical (NLO) polymers must possess large and stable bulk nonlinear properties if they are to be of practical use. Numerous classes of NLO chromophores and polymers have already been evaluate...
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Article
S7.11 Isolation and structural determination of high-molecular-weight glycan units present in egg cortical granular-derived glycoproteins ofbufo japonicus andxenopus inevis
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Article
Cyclic ureas as solvents for poly(aryl ether) synthesis
The synthesis of various poly(aryl ethers) and related small molecule compounds were examined using the cyclic urea 1,3-Dimethyl-3,4,5,6-tetrahydro-2(IH)-pyrimidinone (N,N′-dimethylpropylene urea, DMPU) as the...