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Article
Contact mechanics of a flexible imprinter for photocured nanoimprint lithography
A flexible imprinter can be used to accommodate substrate or template roughness in nanoimprint lithography. The contact mechanics of a multi-layer imprinter incorporating bending and local deformation is descr...
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Article
Porous Organosilicates for On-Chip Dielectric Applications
Porous organosilicates useful for on-chip insulator applications can be prepared by templating the vitrification of low molecular weight silsesquioxanes (SSQs) using highly branched, thermally labile macromole...
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Chapter
Nanoporous Polyimides
Foamed polyimides have been developed in order to obtain thin film dielectric layers with very low dielectric constants for use in microelectronic devices. In these systems the pore sizes are in the nanometer ...
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Article
Recent Advances in Low K Polymeric Materials
As microelectronic device dimensions decrease and functionality density increases, a change in interconnect materials, both conductors and insulators must change from currently used materials. To this end, we ...
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Article
Nanoporous Polyimide Films from Polyimide-Aliphatic Polyester or Polyimide-Aliphatic Polycarbonate Copolymers
We have explored polyimide foams created using a block copolymer approach as part of our research efforts to obtain thin film dielectric layers with very low dielectric constants for use in microelectronic dev...
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Article
Characterization of thin Polymeric Nanofoam films by Transmission Electron Microscopy and Small Angle Neutron Scattering
Thin film polymer nanofoams are produced from triblock copolymers of a fluorinated polyimide, 3F/PMDA (derived from pyromelletic dianhydride (PMDA) and 1,1-bis(4-aminophenyl)-1-phenyl-2,2,2-trifluoroethane (3F...
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Article
Polyimide Nanofoams For Low Dielectric Applications
Foamed polyimides have been developed in order to obtain thin film dielectric layers with very low dielectric constants for use in microelectronic devices. In these systems the pore sizes are in the nanometer ...
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Article
Cyclic ureas as solvents for poly(aryl ether) synthesis
The synthesis of various poly(aryl ethers) and related small molecule compounds were examined using the cyclic urea 1,3-Dimethyl-3,4,5,6-tetrahydro-2(IH)-pyrimidinone (N,N′-dimethylpropylene urea, DMPU) as the...