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Fabrication and chemo-physical characterization of CuO/chitosan nanocomposite-mediated tricomponent PVA films

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Abstract

Copper oxide/chitosan nanocomposite (CCNC) specimens were fabricated via a simple solvent evaporation route. The presence and intercalation of chitosan and CuO within the nanocomposites were explored using advanced analytical techniques of X-ray diffraction, Fourier transform infrared spectroscopy, energy-dispersive X-ray analyses and the scanning electron microscopy. The prepared nanocomposite was then incorporated into poly(vinyl alcohol) (PVA) matrix to fabricate a tricomponent composite. The resultant tricomponent composite was characterized for various chemo–physical and mechanical properties using differential scanning calorimetry (DSC) and the mechanical testing. The DSC results indicated that the glass transition temperature of PVA decreased on incorporating the CCNC into the PVA matrix; this also enhanced the tensile strength and flexibility of the resulting films. The prepared tricomponent films may find potential applications in sensing and catalysis.

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References

  1. Aslam M, Kalyar MA, Raza ZA (2018) Polyvinyl alcohol: a review of research status and use of polyvinyl alcohol based nanocomposites. Polym Eng Sci 58:2119–2132

    Article  CAS  Google Scholar 

  2. Aslam M, Kalyar MA, Raza ZA (2017) Fabrication of reduced graphene oxide nanosheets doped PVA composite films for tailoring their opto-mechanical properties. Appl Phys A 123:424

    Article  Google Scholar 

  3. Aslam M, Kalyar MA, Raza ZA (2019) Investigation of structural and thermal properties of distinct nanofillers-doped PVA composite films. Polym Bull 76:73–86

    Article  CAS  Google Scholar 

  4. Mallapragada SK, Peppas NA (1996) Dissolution mechanism of semicrystalline poly(vinyl alcohol) in water. J Polym Sci B 34:1339–1349

    Article  CAS  Google Scholar 

  5. Paradossi G, Lisi R, Paci M, Crescenzi V (1996) New hydrogels based on poly(vinyl alcohol). J Polym Sci A 34:3417–3425

    Article  CAS  Google Scholar 

  6. Goel A, Rani N (2012) Effect of PVP, PVA and POLE surfactants on the size of iridium nanoparticles. Open J Inorg Chem 2:67–73

    Article  Google Scholar 

  7. Vimala K, Yallapu MM, Varaprasad K, Reddy NN, Ravindra S, Naidu NS, Raju KM (2011) Fabrication of curcumin encapsulated chitosan PVA silver nanocomposite films for improved antimicrobial activity. J Biomater Nanobiotechnol 2:55–64

    Article  CAS  Google Scholar 

  8. Aslam M, Kalyar MA, Raza ZA (2018) Investigation of zinc oxide-loaded poly(vinyl alcohol) nanocomposite films in tailoring their structural, optical and mechanical properties. J Electron Mater 47:3912–3926

    Article  CAS  Google Scholar 

  9. Aslam M, Kalyar MA, Raza ZA (2018) Effect of separate zinc, copper and graphene oxides nanofillers on electrical properties of PVA based composite strips. J Electron Mater 48:1116–1121

    Article  Google Scholar 

  10. Mallakpour S (2015) Poly(vinyl alcohol) chains grafted onto the surface of copper oxide nanoparticles: application in synthesis and characterization of novel optically active and thermally stable nanocomposit based on poly (amide-imide) containing N-trimellitylimido-l-valine linkage. Int J Polym Anal Charact 20:82–97

    Article  CAS  Google Scholar 

  11. Javid A, Raza ZA, Hussain T, Rehman A (2014) Chitosan microencapsulation of various essential oils to enhance the functional properties of cotton fabric. J Microencapsul 31:461–468

    Article  CAS  Google Scholar 

  12. Pyun J, Matyjaszewski K (2001) Synthesis of nanocomposite organic/inorganic hybrid materials using controlled radical polymerization. Chem Mater 13:3436–3448

    Article  CAS  Google Scholar 

  13. Raza ZA, Rehman A, Mohsin M, Bajwa SZ, Anwar F, Naeem A, Ahmad N (2015) Development of antibacterial cellulosic fabric via clean impregnation of silver nanoparticles. J Clean Prod 101:377–386

    Article  CAS  Google Scholar 

  14. Kong H, Jang J (2008) Antibacterial properties of novel poly(methyl methacrylate) nanofiber containing silver nanoparticles. Langmuir 24:2051–2056

    Article  CAS  Google Scholar 

  15. Moura MRD, Aouada FA, Avena-Bustillos RJ, McHugh TH, Krochta JM, Mattoso LH (2009) Improved barrier and mechanical properties of novel hydroxypropyl methylcellulose edible films with chitosan/tripolyphosphate nanoparticles. J Food Eng 92:448–453

    Article  Google Scholar 

  16. Goyal A, Kumar A, Patra PK, Mahendra S, Tabatabaei S, Alvarez PJ, John G, Ajayan PM (2009) In situ synthesis of metal nanoparticle embedded free standing multifunctional PDMS films. Macromol Rapid Commun 30:1116–1122

    Article  CAS  Google Scholar 

  17. Sutradhar P, Saha M, Maiti D (2014) Microwave synthesis of copper oxide nanoparticles using tea leaf and coffee powder extracts and its antibacterial activity. J Nanostruct Chem 4:1–6

    Article  Google Scholar 

  18. Divya R, Meena M, Mahadevan CK, Padma CM (2014) Investigation on CuO dispersed PVA polymer films. Int J Eng Res Appl 4:1–7

    Google Scholar 

  19. Ren G, Hu D, Cheng EWC, Vargas-Reus MA, Reip P, Allaker RP (2009) Characterisation of copper oxide nanoparticles for antimicrobial applications. Int J Antimicrob Agents 33:587–590

    Article  CAS  Google Scholar 

  20. Mankad V, Kumar RK, Jha PK (2013) Investigation of blue-shifted plasmon resonance: an optical properties study of silver nanoparticles. Nanosci Nanotechnol Lett 5:889–894

    Article  CAS  Google Scholar 

  21. Aslam M, Kalyar MA, Raza ZA (2016) Synthesis and structural characterization of separate graphene oxide and reduced graphene oxide nanosheets. Mater Res Exp 3:105036

    Article  Google Scholar 

  22. Raza ZA, Anwar F, Ahmad S, Aslam M (2016) Fabrication of ZnO incorporated chitosan nanocomposites for enhanced functional properties of cellulosic fabric. Mater Res Exp 3(11):115001

    Article  Google Scholar 

  23. Rao JK, Raizada A, Ganguly D, Mankad MM, Satayanarayana SV, Madhu GM (2015) Investigation of structural and electrical properties of novel CuO-PVA nanocomposite films. J Mater Sci 50:7064–7074

    Article  CAS  Google Scholar 

  24. Ramesh C, Hariprasad M, Ragunathan V, Jayakumar N (2012) A novel route for synthesis and characterization of green Cu2O/PVA nanocomposites. Eur J Appl Eng Sci Res 1:201–206

    CAS  Google Scholar 

  25. Zivanovic S, Li J, Davidson PM, Kit K (2007) Physical, mechanical, and antibacterial properties of chitosan/PEO blend films. Biomacromol 8:1505–1510

    Article  CAS  Google Scholar 

  26. Zubair M, Najeeb F, Mohamed M, Saeed A, Ramis MK, Abdul-Mujeeb MS, Saro**i BK (2014) Analysis of chitosan polymer doped with nano Al2O3 and nano CuO. Am J Polym Sci 4:40–45

    Google Scholar 

  27. Orts WJ, Shey J, Imam SH, Glenn GM, Guttman ME, Revo JF (2005) Application of cellulose microfibrils in polymer nanocomposites. J Polym Environ 13:301–306

    Article  CAS  Google Scholar 

  28. Bahrami SB, Kordestani SS, Mirzadeh H, Mansoori P (2003) Poly (vinyl alcohol)-chitosan blends: preparation, mechanical and physical properties. Iran Polym J 12:139–146

    CAS  Google Scholar 

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Correspondence to Zulfiqar Ali Raza.

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Aslam, M., Raza, Z.A. & Siddique, A. Fabrication and chemo-physical characterization of CuO/chitosan nanocomposite-mediated tricomponent PVA films. Polym. Bull. 78, 1955–1965 (2021). https://doi.org/10.1007/s00289-020-03194-4

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  • DOI: https://doi.org/10.1007/s00289-020-03194-4

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