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Coordination Polymerization
Nearly half of all polymers produced worldwide (according to production volume) are produced by catalytic polymerization reactions carried out in the...
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Free Radical Polymerization of Dimethyl Amino Ethyl Methacrylate Initiated by Poly(3-hydroxybutyrate-co-3-hydroxyhexanoate) Macroazo Initiator: Thermal and Physicochemical Characterization
A novel macro intermediate based on poly(3-hydroxybutyrate- co -3-hydroxyhexanoate) (PHBHHx) was synthesized for use in the copolymerization with...
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Chemoselective and Living/Controlled Polymerization of Alkenyl Methacrylates by the Phosphonium Ylide/Organoaluminum Lewis Pairs
Chemoselective, living/controlled polymerizations of allyl methacrylate (AMA) and vinyl methacrylate (VMA) with/without methyl methacrylate (MMA) by...
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Tailoring sulfur-doped and nitrogen-defective carbon nitride nanosheets for efficient photo-controlled radical polymerizations
Despite the challenges that remain, the synergistic adjustment of various microstructures and photochemical parameters of graphitic carbon nitride...
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Enzymatic Polymerization to Polysaccharides
Polysaccharides are formed by repeated glycosylations between a sugar donor and a sugar acceptor. This chapter reviews the in vitro synthesis of...
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A combination of surface-initiated controlled radical polymerization (SET-LRP) and click-chemistry for the chemical modification and fluorescent labeling of cellulose nanofibrils: STED super-resolution imaging of a single fibril and a single fibril embedded in a composite
A strategy is developed to modify cellulose nanofibril (CNF) surfaces with a combination of Cu 0 -mediated radical polymerization (SET-LRP) and Cu I -cata...
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Facile synthesis of gradient copolymers enabled by droplet-flow photo-controlled reversible deactivation radical polymerization
Monomer sequence influences the properties and applications of polymers. Consequently, massive efforts have been made to implement sequence control...
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N- and C-diallyl monomers of new structural types in radical polymerization: theoretical study on the mechanism of reaction
The cyclization and competing reactions for growing radical chains based on N -and C -diallyl monomers of new structural types have been investigated...
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Recent Advances in ADMET Polymerization
Acyclic diene metathesis (ADMET) polymerization techniques and methodologies developed over the past five years are reviewed. Through constant...
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Synthesis of Ethylene–Vinyl Acetate Copolymers by Reversible Addition–Fragmentation Chain-Transfer Radical Polymerization
AbstractReversible addition–fragmentation chain-transfer radical copolymerization of ethylene with vinyl acetate in the presence of...
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Polymer Brushes by Anionic and Cationic Surface-Initiated Polymerization (SIP)
The formation of homopolymer and block copolymer brushes grafted from flat and nanoparticle surfaces via surface-initiated anionic and cationic...
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Polymer-modified regenerated cellulose membranes: following the atom transfer radical polymerization concepts consistent with the principles of green chemistry
AbstractSynthetic routes for functionalization of cellulose membranes by polymer chains characterized by controlled structures are constantly...
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Synthesis of block copolymer of vinyl acetate and methyl acrylate by cobalt-mediated radical polymerization in a packed column system: simultaneous control of molecular weight, separation, and purification
In this study, for the first time, we investigate cobalt-mediated radical block copolymerization of vinyl acetate (VAc) and methyl acrylate (MA) in a...
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Features of Polymerization of Methyl Methacrylate in the Presence of New Ruthenium(II) and Ruthenium(III) Carborane Complexes with Chelate P‒O‒P Ligands
AbstractThe radical polymerization of methyl methacrylate by the atom transfer radical polymerization (ATRP) mechanism under the action of systems...
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Controlled Ring-Expansion Polymerization Based on Acyl-Transfer Polymerization of Thiiranes with Aromatic Heterocycles as Initiators
This chapter describes the ring-expansion polymerization (REP) of thiiranes using aromatic benzothiazolone derivatives as initiators, including key...
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Molar Mass Dispersity Control by Iodine-mediated Reversible-deactivation Radical Polymerization
Dispersity ( Đ ) of polymers has a great effect on the properties of polymeric materials, and therefore how to control Đ is very important but still a...
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Dual-responsive polymers synthesized via RAFT polymerization for controlled demulsification and desorption
Intelligent polymers responsive to the environment have aroused widespread interest in many applications of materials and interfaces. However,...
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Liquid Crystalline Polymers by Metathesis Polymerization
Liquid crystalline polymers (LCPs) have gained attention as materials with interesting optical, mechanical and rheological properties. This review...
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In Vitro Enzyme-Induced Vinyl Polymerization
The in vitro enzyme-mediated polymerization of vinyl monomers is reviewed with a scope covering enzymatic polymerization of vitamin C...
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Features of Methyl Methacrylate Polymerization Mediated by Methylene Blue and Ethyl 2-Bromoisobutyrate under Photoirradiation Conditions
AbstractUsing methyl methacrylate polymerization as an example, the features of polymer synthesis in the presence of the catalytic system [methylene...
