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Free Radical Polymerization of Dimethyl Amino Ethyl Methacrylate Initiated by Poly(3-hydroxybutyrate-co-3-hydroxyhexanoate) Macroazo Initiator: Thermal and Physicochemical Characterization

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Abstract

A novel macro intermediate based on poly(3-hydroxybutyrate-co-3-hydroxyhexanoate) (PHBHHx) was synthesized for use in the copolymerization with dimethyl amino ethyl methacrylate (DMAEMA). Methyl amino ethanol was reacted with PHBHHx to prepare a dihydroxy terminated polyester. The hydroxyl ends of the obtained PHBHHx derivatives were capped with 4,4’-azobis cyanopentanoic acid to obtain the PHBHHx macroazo initiator (PHBHHx-AI) for free radical copolymerization of DMAEMA at 70oC. A steady increase in DMAEMA units in the synthesized block copolymer as a function of time was observed. The overall rate constants for the free radical polymerization of DMAEMA initiated by PHBHHx-AI was k = 2.33 × 10− 4 Lmol-1s-1. Block copolymers were characterized using the 1 H NMR, FTIR, DSC and TGA techniques.

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Acknowledgements

This work was supported by the Kapadokya University Research Funds (#KÜN.2020-BAGP-001).

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Authors and Affiliations

  1. Department of Aircraft Airframe Engine Maintenance, Kapadokya University, 50420 Ürgüp, Nevşehir, Turkey

    Baki Hazer

  2. Department of Chemistry, Zonguldak Bülent Ecevit University, 67100, Zonguldak, Turkey

    Baki Hazer

  3. CNRS, Inst Chim & Mat Paris Est, UMR 7182, 2-8 Rue Henri Dunant, University of Paris Est, F-94320, Thiais, France

    Tina Mod**ou & Valérie Langlois

  4. Department of Science Education, Van Yüzüncü Yıl University, Van, 65100, Turkey

    Melahat Göktaş

  5. Fac Vet Med, Dept Food Hyg & Technol, Burdur Mehmet Akif Ersoy Univ, Istiklal Campus, 15030, Burdur, Turkey

    Fulya Taşçı

  6. United States Department of Agriculture, Agricultural Research Service, Eastern Regional Research Center, 600 East Mermaid Lane, Wyndmoor, PA, 19038, USA

    Richard D. Ashby

  7. Center for Analysis and Synthesis, Dept Chem, Lund University, S-22100, Lund, Sweden

    Baozhong Zhang

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  1. Baki Hazer
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  2. Tina Mod**ou
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  3. Valérie Langlois
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  4. Melahat Göktaş
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  5. Fulya Taşçı
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  6. Richard D. Ashby
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  7. Baozhong Zhang
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Contributions

Baki Hazer: Supervision, Conceptualization. Fulya Taşçı: Conceptualization. Valerie Langlois: Conceptualization, Supervision. Tina Mod**ou: Conceptualization. Richard Ashby: Conceptualization, Supervision. Melahat Göktaş: Conceptualization. Baozhong Zhang: Conceptualization.

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Correspondence to Baki Hazer or Melahat Göktaş.

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Hazer, B., Mod**ou, T., Langlois, V. et al. Free Radical Polymerization of Dimethyl Amino Ethyl Methacrylate Initiated by Poly(3-hydroxybutyrate-co-3-hydroxyhexanoate) Macroazo Initiator: Thermal and Physicochemical Characterization. J Polym Environ 31, 3688–3699 (2023). https://doi.org/10.1007/s10924-023-02857-3

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