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Article
Novel Pd/Al2O3–CeO2 Nanosheets for One-Pot Synthesis of Methyl Isobutyl Ketone from Acetone
A Pd/Al2O3–CeO2 nanosheets catalyst was fabricated successfully via coprecipitation strategy for the one-pot conversion of acetone to methyl isobutyl ketone (MIBK). Compared with Pd/Al2O3 or Pd/CeO2, Pd/Al2O3–CeO
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Article
Ternary SO42−–ZrO2–TiO2 Solid Super Acid Catalyst for One-Step Synthesis of Adipicdihydrazide
An efficient SO42−–ZrO2–TiO2 super acid catalyst was fabricated via simple impregnation precipitation strategy and applied in one-step synthesis of adipicdihydrazide (ADH). The purity and yield of ADH reached up ...
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Article
Peroxotungstate-Based Ionic Hybrid as a Triphase Heterogeneous Catalyst for Efficient Benzyl Alcohol Oxidation Under Mild Conditions
Supported ionic-liquid-phases (SILPs) were synthesized via reaction of 1-methyl-3-(3-triethoxysilylpropyl)imidazolium hexafluorophosphate (ImCl-PF6) with SBA-15 and then peroxotungstate molecules were immobilized...
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Article
Hydrogenation Performance of Acetophenone to 1-Phenylethanol on Highly Active Nano Cu/SiO2 Catalyst
In this work, highly active nano Cu/SiO2 catalysts with various copper content were prepared by urea homogeneous precipitation method. The catalysts were characterized by N2 adsorption, XRD, H2-TPR, XPS and TEM. ...
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Article
Synthesis of Convertible {PO4[WO3 \(\rightleftharpoons\) W(O)2(O2)]4}-DMA16 in SBA-15 Nanochannels and Its Catalytic Oxidation Activity
A phase transfer catalyst ({PO4[WO3]4}-DMA16) had been first synthesized and stabilized in mesochannels of (3-chloropropyl)trimethoxysilane-functionalized mesoporous silica SBA-15 to build an active nano-environm...
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Article
Immobilization of tungsten chelate complexes on functionalized mesoporous silica SBA-15 as heterogeneous catalysts for oxidation of cyclopentene
An efficient hybrid mesoporous heterogeneous catalyst system was synthesized via covalently grafting tungsten chelate complex W-N,N (N,N = (3-triethoxysilylpropyl) [3-(2-pyridyl)-1-pyrazolyl] acetamide, N,N-chela...
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Article
Tungsten-based organic mesoporous SBA-15 materials: characterization and catalytic properties in the oxidation of cyclopentene to glutaric acid with H2O2
A series of hybrid heterogeneous catalysts were prepared and their catalytic performance was investigated for the first time in the green oxidation of cyclopentene to glutaric acid (GAC) using 50 wt% H2O2. After ...
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Article
Hydroesterification of ethylene oxide catalyzed by 1-butyl-3-methylimidazolium cobalt tetracarbonyl ionic liquid
In this paper, functional ionic liquid 1-butyl-3-methylimidazolium cobalt tetracarbonyl [Bmim][Co(CO)4] is prepared in a metathesis reaction between [Bmim]Cl and KCo(CO)4. The structure of [Bmim]+ is illustrated ...