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  1. No Access

    Article

    Rh Complex with Unique Rh–Al Direct Bond: Theoretical Insight into its Characteristic Features and Application to Catalytic Reaction via σ-Bond Activation

    A new type of catalyst for reactions via σ-bond activation is Rh(PAlP): Rh-Al heterobimetallic complex of diphosphine-based tridentate pincer-type PAlP ligand bearing an aluminyl moiety at the center coordinat...

    Qiao-Zhi Li, Naofumi Hara, Kazuhiko Semba, Yoshiaki Nakao… in Topics in Catalysis (2022)

  2. No Access

    Article

    Nickel-catalysed anti-Markovnikov hydroarylation of unactivated alkenes with unactivated arenes facilitated by non-covalent interactions

    Anti-Markovnikov additions to alkenes have been a longstanding goal of catalysis, and anti-Markovnikov addition of arenes to alkenes would produce alkylarenes that are distinct from those formed by acid-cataly...

    Noam I. Saper, Akito Ohgi, David W. Small, Kazuhiko Semba… in Nature Chemistry (2020)

  3. No Access

    Chapter

    Catalytic C–CN Bond Activation

    Synthetic organic reactions through C–CN activation by transition metal catalysis are reviewed. C–CN bond activation by metal complexes proceeds mainly via two pathways; oxidative addition and C–CN cleavage ac...

    Yoshiaki Nakao in C-C Bond Activation (2014)

  4. No Access

    Chapter and Conference Paper

    Design of the High-Tc Superconducting Model Cable

    We designed high-Tc superconducting model cable considering current distribution, being based on the concept of cooling. For conductor and shield conductor, we designed transposed segments from the point of vi...

    Atsushi Kume, Shigeo Nagaya, Takenori Nakajima… in Advances in Superconductivity X (1998)