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    Rh Complex with Unique Rh–Al Direct Bond: Theoretical Insight into its Characteristic Features and Application to Catalytic Reaction via σ-Bond Activation

    A new type of catalyst for reactions via σ-bond activation is Rh(PAlP): Rh-Al heterobimetallic complex of diphosphine-based tridentate pincer-type PAlP ligand bearing an aluminyl moiety at the center coordinat...

    Qiao-Zhi Li, Naofumi Hara, Kazuhiko Semba, Yoshiaki Nakao in Topics in Catalysis (2022)