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    Article

    Rh Complex with Unique Rh–Al Direct Bond: Theoretical Insight into its Characteristic Features and Application to Catalytic Reaction via σ-Bond Activation

    A new type of catalyst for reactions via σ-bond activation is Rh(PAlP): Rh-Al heterobimetallic complex of diphosphine-based tridentate pincer-type PAlP ligand bearing an aluminyl moiety at the center coordinat...

    Qiao-Zhi Li, Naofumi Hara, Kazuhiko Semba, Yoshiaki Nakao… in Topics in Catalysis (2022)

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    Article

    Nickel-catalysed anti-Markovnikov hydroarylation of unactivated alkenes with unactivated arenes facilitated by non-covalent interactions

    Anti-Markovnikov additions to alkenes have been a longstanding goal of catalysis, and anti-Markovnikov addition of arenes to alkenes would produce alkylarenes that are distinct from those formed by acid-cataly...

    Noam I. Saper, Akito Ohgi, David W. Small, Kazuhiko Semba… in Nature Chemistry (2020)