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Article
Electrochemical and Luminescent Properties of New Mononuclear Ruthenium(II) and Binuclear Iridium(III)-Ruthenium(II) Terpyridine Complexes
Hexafluorophosphate salts of mononuclear complexes [RuIICl(L)(terpy)]+ (L = dmbpy (1); dpbpy (2), sambpy (3), and dpp (7), and binuclear complexes [RuII2Cl2(dpp)(terpy)2]2+ (8) and [IrIIIRuIICl2(dpp)(terpy)2]3+ (
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Article
Electrochemical and Phosphorescent Properties of New Ir(III) Complexes Coordinated by Various Bipyridine Derivatives
Four useful polypyridine iridium(III) complexes in the form of [IrCl2L2]+ were prepared and their spectroscopic and electrochemical properties as well as X-ray crystallography were investigated. The ligands used ...
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Article
Erratum: Mechanism of metal activation of human hematopoietic prostaglandin D synthase
Nat. Struct. Biol. 10, 291–296 (2003). The y-axes of Fig. 3a,b,d in this manuscript were labeled incorrectly. The correct unit for the PDGS activity in these panels should be μmol min−1 mg−1 protein. Additiona...
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Article
Mechanism of metal activation of human hematopoietic prostaglandin D synthase
Here we report the crystal structures of human hematopoietic prostaglandin (PG) D synthase bound to glutathione (GSH) and Ca2+ or Mg2+. Using GSH as a cofactor, prostaglandin D synthase catalyzes the isomerizatio...
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Article
Reversible Photodimerization of Ester Derivatives of Thymine Having Long Alkyl Chains in Solid Film
Reversible photodimerizations of ester derivatives of thymine having long alkyl chains were studied in thin solid film. The spin coated thin film of thymine compounds gave the photodimer under irradiation of U...
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Article
Spectroscopic and electrochemical properties of two azurins (Az-iso1 and Az-iso2) from the obligate methylotroph Methylomonas sp. strain J and the structure of novel Az-iso2
sp. strain J gives rise to two azurins (Az-iso1 and Az-iso2) with methylamine dehydrogenase (MADH-Mj). The intense blue bands characteristic of Az-iso1 and Az-iso2 are observed at 621 and 616 nm in the visibl...
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Chapter
Crystal Structure of Rubisco from a Thermophilic Red Alga, Galdieria Partita
Ribulose 1,5-bisphosphate carboxylase/oxygenase (RuBisCO, EC 4.1.1.39) is the initial step enzyme in the Calvin-Benson cycle of photosynthesis. It catalyzes the addition of gaseous CO2 to ribulose 1,5-bisphosphat...
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Chapter
Three-Dimensional Structure of Phosphoenolpyruvate Carboxylase from Escherichia coli at 2.8Å Resolution
Phosphoenolpyruvate carboxylase (PEPC; EC 4.1.1.31) irreversibly catalyzes the carboxylation of phosphoenolpyruvate to form oxaloacetate and inorganic phosphate using Mg2+ as a cofactor.
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Article
Magnetic Properties in Charge-Transfer Complexes of High-Symmetry Organic Acceptors
Tris(l, 2-benzodithio)- and tris(l, 2-ethylenedithio)-trimethylenemethane dication salts were synthesized for the purpose of using as an acceptor in the formation of charge-transfer (CT) complexes with some di...