195 Result(s)
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Article
Regioselective Synthesis of New [1,3]Thiazolo- and [1,3]Selenazolo[3,2-a]pyridinium Derivatives
The reactions of pyridine-2-sulfenyl and pyridine-2-selenenyl halides with heteroatomic vinyl compounds were used as a basis for the development of effective regioselective methods for the synthesis of new fus...
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Article
Testing the Hypothesis about the Existence of a Planet Orbiting the Pulsar B0329+54 (J0332+5434)
We have analyzed the results of our observations of the millisecond pulsar B0329+54 (J0332+5434), which exhibits quasi-periodic variations in the barycentric times of arrival (TOAs) of pulses on long time scal...
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Article
Regioselective Reactions of Pyridine-2-sulfenyl Bromide with Vinyl and Allyl Ethers
Annulation reactions of pyridine-2-sulfenyl bromide with vinyl and allyl ethers proceeded regioselectively, but with opposite regiochemistry. Reactions with vinyl ethers led to 3-organyloxy-2,3-dihydro[1,3]thi...
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Article
Synthesis of 2,6-Dibromo-9-selenabicyclo[3.3.1]nonane-Based Pyridinium Salts Containing Acetal Groups
An efficient one-pot procedure has been developed for the synthesis of previously unknown 1,1′-(9-selenabicyclo[3.3.1]nonane-2,6-diyl)dipyridinium dibromides containing acetal moieties via transannular additi...
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Article
On Long-Term Variations in Solar Wind and Solar Activity Parameters with Possible Application to the Global Climate Problem
According to the data on the 20–24 solar activity cycles, long-term variations in the annual average solar wind speed and interplanetary scintillation index are compared to Wolf number variations. It is shown ...
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Article
Effect of a Synthetic Organoselenium Compound on Post-Vaccination Immunopoiesis in the Red Bone Marrow and Cell Composition of Peripheral Blood of White Mice Vaccinated with Yersinia pestis EV
We studied the effect of an experimental synthetic organoselenium compound 2,6-dipyridinium- 9-selenabicyclo[3.3.1]nonane dibromide (974zh) on the cell composition of the red bone marrow and peripheral blood i...
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Article
One-Pot Syntheses of Functionalized Dihydrobenzoselenophenes and Selenochromans from Acetyl Eugenol and Selenium Dibromide. Rearrangement of 2-(Bromomethyl)-2,3-dihydro-1-benzoselenophene to Selenochromans
Efficient methods for the synthesis of new fused heterocyclic compounds have been developed on the basis of annulation–functionalization of acetyl eugenol with selenium dibromide. The proposed procedures make ...
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Article
One-Pot Synthesis of Functionalized 1,1′-(9-Selenabicyclo[3.3.1]nonane-2,6-diyl)dipyridinium Dibromides
Previously unknown functionally substituted 1,1′-(9-selenabicyclo[3.3.1]nonane-2,6-diyl)dipyridinium dibromides were synthesized in 90–98% yields by one-pot condensation of selenium dibromide, cycloocta-1,5-...
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Article
Efficient Synthesis of 2-[(Alkyltellanyl)methyl]-2,3-dihydro-1-benzofurans from Tellurium Tetrahalides and 2-Allylphenols
Efficient methods have been proposed for the synthesis of 2-[(alkyltellanyl)methyl]-2,3-dihydro-1-benzofurans in up to 90% yield through generation of (2,3-dihydro-1-benzofuran-2-yl)methanetellurolate ions fro...
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Article
Stereoselective synthesis of functionalized divinyl sulfides based on sulfur dichloride and (trimethylsilyl)acetylene
Sulfur dichloride reacts with (trimethylsilyl)acetylene to form stereoselectively E, E-bis-(2-chloro-2-trimethylsilylvinyl) sulfide and isomeric E-2-chloro-2-trimethylsilylvinyl E-2-chloro-1-trimethylsilylvinyl s...
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Article
Synthesis of Functional Dihydro-1,4-benzoxaselenines from Carvacrol Allyl Ether and Selenium Dihalides
One-step procedures have been developed for the selective synthesis of functionalized 2,3-dihydro-1,4-benzoxaselenines in 90–98% yields by cyclization of carvacrol allyl ether with selenium dihalides. Annulati...
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Article
Principles of Pulsar Space Navigation
The paper considers the principles of space navigation using pulsars observed in the radio range. The requirements for receiving equipment are outlined, a recommended pulsar list is given, and an algorithm for...
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Article
Immunotropic Properties of an Experimental Synthetic Selenium-Organic Compound
We studied immunotropic properties of synthetic selenium-organic preparation 2,6-dipyridinium-9-selenabicyclo[3.3.1]nonyl dibromide (974zh). The experimental preparation reduced the cAMP/cGMP ratio, which indi...
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Article
Assembling of Thiazolo[3,2-a]pyridinium Salts via the Reaction of 2-Pyridinesulfenyl Halides with Vinyl Ethyl Ether
The regio- and stereoselective synthesis of 3-ethoxy-2H,3H-[1,3]thiazolo[3,2-a]pyridin-4-ium halides via the reaction of 2-pyridinesulfenyl halides with vinyl ethyl ether has been elaborated.
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Article
Effect of Synthetic Organoselenium Drug on the Degree of Pathological Changes in the Organs of White Mice Immunized with Tularemia and Brucellosis Vaccines
We studied the effect of the organoselenium compound 2,6-dipyridinium-9-selenium-bicyclo[ 3,3,1]nonan dibromide (974zh) on the severity of pathological changes in the organs of experimental animals immunized w...
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Article
Regio- and stereoselective reaction of sodium benzeneselenolate with 3-(trimethylsilyl)prop-2-ynamides
Sodium benzeneselenolate adds regio- and stereoselectively to 3-(trimethylsilyl)prop-2-yn-amides to give (Z)-3-(phenylselanyl)prop-2-enamides.
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Article
Synthesis of (1,3-oxathiolan-2-ylmethyl) sulfide and disulfide by cyclofunctionalization of 2-(vinylsulfanyl)ethanol with sulfur dichloride and monochloride
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Article
Regio- and Stereoselective Addition of Selenium Dichloride to Alkyl Propiolates
The reaction of selenium dichloride with methyl and ethyl propiolates leads to formation of anti-Markovnikov adducts. The regio- and stereoselective synthesis of hitherto unknown bis[(E)-2-chloro-1-(alkoxycarbony...
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Article
Alkoxytelluration of Styrene with Tellurium Tetrahalides
An efficient synthesis of the earlier unknown trichloro- and tribromo(2-ahkoxy-2-phenylethyl)-λ4-tellanes with yields of 90 to 100% has been developed basing on alkoxytelluration of styrene with tellurium tetrach...
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Article
Regio- and Stereoselective Synthesis of (E)-2-Bromo-1-(phenoxymethyl)vinyltellanes
Regio- and stereoselective synthesis of tribromo[(E)-2-bromo-1-(phenoxymethyl)vinyl]tellane based on the reaction of tellurium tetrabromide with propargyl phenyl ether has been elaborated. This reaction is the fi...