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Regio- and Stereoselective Addition of Selenium Dichloride to Alkyl Propiolates

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Abstract

The reaction of selenium dichloride with methyl and ethyl propiolates leads to formation of anti-Markovnikov adducts. The regio- and stereoselective synthesis of hitherto unknown bis[(E)-2-chloro-1-(alkoxycarbonyl)vinyl]selenides has been developed based on this reaction.

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Acknowledgments

The authors are grateful to the Baikal Analytical Center for Collective Use, Siberian Branch, Russian Academy of Sciences, for spectral and analytical studies.

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Authors and Affiliations

  1. Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, Irkutsk, ul. Favorskogo 1, 664033, Russia

    M. V. Musalov, V. A. Yakimov, V. A. Potapov, M. V. Andreev & S. V. Amosova

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  1. M. V. Musalov
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  2. V. A. Yakimov
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  3. V. A. Potapov
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  4. M. V. Andreev
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  5. S. V. Amosova
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Corresponding author

Correspondence to V. A. Potapov.

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The authors declare no conflict of interest.

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Russian Text © The Author(s), 2019, published in Zhurnal Organicheskoi Khimii, 2019, Vol. 55, No. 11, pp. 1800–1803.

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Musalov, M.V., Yakimov, V.A., Potapov, V.A. et al. Regio- and Stereoselective Addition of Selenium Dichloride to Alkyl Propiolates. Russ J Org Chem 55, 1809–1811 (2019). https://doi.org/10.1134/S1070428019110277

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  • DOI: https://doi.org/10.1134/S1070428019110277

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