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  1. No Access

    Article

    Synthesis of platinum-mercury clusters and the molecular structure of Pt4(HgBr)2(μ-CO)4(PPh3)4

    New platinum-mercury clusters, Pt4(HgX)2(μ-CO)4(PR3)4 (X=Cl, Br, I, CF3, or CCl3; R=Ph or Et), were synthesized. The molecular and crystal structure of the Pt4(HgBr)2(μ-CO)4(PPh3)4 cluster was established by X-ra...

    N. K. Eremenko, S. S. Kurasov, A. V. Virovets, T. Struchkov… in Russian Chemical Bulletin (1997)

  2. No Access

    Article

    Redox reactions involving low-valence transition metal complexes: Palladium and platinum phosphinecarbonyl clusters in the synthesis of binuclear compounds

    The heterobinuclear complex, PtPdCl2(μ2-CO)(PPh3)3 was obtained by the redox addition of Pd4(CO)5(PPh3)4, and Pt4(CO)5(PPh3)4, to MCl2(PPh3)2, where M=Pd and Pt, as a single isomer containing the two PPh3 ligands...

    V. V. Bashilov, E. G. Mednikov… in Bulletin of the Academy of Sciences of the… (1987)

  3. No Access

    Article

    Reaction of [Pt(CO)2]n with triarylphosphines

    1. The reaction of platinum dicarbonyl with triarylphosphines has afforded the clusters Pt3(CO)3(PAr3)4 and Pt5(...

    N. K. Eremenko, S. S. Kurasov… in Bulletin of the Academy of Sciences of the… (1986)

  4. No Access

    Article

    Synthesis of Pt(0)-carbonyltrialkylphosphine clusters

    The reaction of platinum dicarbonyl with triethylphosphine gave Pt(0) clusters of composition: Pt5(CO)6(PEt3)4 and Pt4(CO)5(PEt3)4. Treatment of the latter with PEt3 gave the Pt3(CO)3(PEt3)4, cluster.

    N. K. Eremenko, E. G. Mednikov… in Bulletin of the Academy of Sciences of the… (1983)