Conclusions
The heterobinuclear complex, PtPdCl2(μ2-CO)(PPh3)3 was obtained by the redox addition of Pd4(CO)5(PPh3)4, and Pt4(CO)5(PPh3)4, to MCl2(PPh3)2, where M=Pd and Pt, as a single isomer containing the two PPh3 ligands at the platinum atom.
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Literature cited
N. K. Eremenko, E. G. Mednikov, and S. S. Kurasov, Usp. Khim.,54, 671 (1985).
V. V. Bashilov, E. G. Mednikov, V. I. Sokolov, et al., Izv. Akad. Nauk SSSR, Ser. Khim., 923 (1983).
V. V. Bashilov, V. I. Sokolov, and O. A. Reutov, Izv. Akad. Nauk SSSR, Ser. Khim., 2069 (1982).
O. N. Temkin and L. G. Bruk, Usp. Khim.,52, 206 (1983).
R. J. Goodfellow, I. R. Herbert, and A. G. Orpen, J. Chem. Soc., Chem. Commun., 1386 (1983).
R. Bender, P. Braunstein, A. Tiripicchio, and C. M. Tiripicchio, J. Chem. Soc., Chem. Commun., 42 (1984).
P. G. Pringle and B. L. Shaw, J. Chem. Soc., Dalton Trans., 889 (1983).
C. E. Briant, D. I. Gilmour, and D. M. P. Mingos, J. Organomet. Chem.,308, 381 (1986).
P. S. Pregosin and R. Kunz,13P and13C NMR of Transition Metal Phosphine Complexes, Springer Verlag, New York (1979).
E. G. Mednikov and N. K. Eremenko, Izv. Akad. Nauk SSSR, Ser. Khim., 2781 (1984).
J. Chatt and P. Chini, J. Chem. Soc., A, 1538 (1970).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2360–2362, October, 1987.
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Bashilov, V.V., Mednikov, E.G., Kurasov, S.S. et al. Redox reactions involving low-valence transition metal complexes: Palladium and platinum phosphinecarbonyl clusters in the synthesis of binuclear compounds. Russ Chem Bull 36, 2188–2190 (1987). https://doi.org/10.1007/BF00962024
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DOI: https://doi.org/10.1007/BF00962024