Conclusions
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1.
The reaction of platinum dicarbonyl with triarylphosphines has afforded the clusters Pt3(CO)3(PAr3)4 and Pt5(CO)6(PAr3)4.
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2.
In aqueous-acetone solution, in the presence of ammonia, platinum dicarbonyl is present in the form [Pt3(CO)6]5 2−.
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3.
In the first step of the reaction of triarylphosphites with [Pt3(CO)6]5 2− the clusters [Pt3(CO)6]3 2− and Pt3(CO)3(PAr3)4 are formed.
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N. K. Eremenko, E. G. Mednikov, S. S. Kurasov, and S. P. Gubin, Izv. Akad. Nauk SSSR, Ser. Khim., 682 (1983).
J.-P. Barbier, R. Bender, P. Braunstein, J. Fisher, and L. Richard, J. Chem. Res. (M), 2910 (1978).
G. Longoni and P. Chini, J. Am. Chem. Soc.,98, 7225 (1976).
D. M. Washecheck, E. J. Wucherer, L. F. Dahl, G. Longoni, M. Manassero, M. Mansoni, and P. Chini, J. Am. Chem. Soc.,101, 6110 (1979).
P. Chini, J. Organometal. Chem.,200, 37 (1980).
J. Chatt and P. Chini, J. Chem. Soc., A, 1538 (1970).
E. G. Mednikov and N. K. Eremenko, Izv. Akad. Nauk SSSR, Ser. Khim., 2540 (1982).
R. Bender and P. Braunstein, J. Chem. Soc., Chem. Communs., 334 (1983).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 659–662, March, 1986.
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Eremenko, N.K., Kurasov, S.S., Mednikov, E.G. et al. Reaction of [Pt(CO)2]n with triarylphosphines. Russ Chem Bull 35, 602–605 (1986). https://doi.org/10.1007/BF00953235
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DOI: https://doi.org/10.1007/BF00953235