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  1. No Access

    Article

    Synthesis of large palladium clusters. The preparation of Pd38(CO)28(PR3)12 (R = Et, Bun) and Pd34(CO)24(PEt3)12

    Several methods for the synthesis of the Pd38(CO)28L12 cluster (L = PEt3) by treatment of Pd10(CO)12L6 with CF3COOH-Me3NO, CF3COOH-H2O2, Pd(OAc)2-Me3NO, and Pd2(dba)3 mixtures (dba is dibenzylideneacetone) were p...

    E. G. Mednikov, N. I. Kanteeva in Russian Chemical Bulletin (1995)

  2. No Access

    Article

    Synthesis of big palladium clusters. Preparation of Pd23(CO)20(PEt3)8

    Selective methods for the synthesis of the cluster Pd23(CO)20L8, L=PEt3, have been suggested. The compound has been prepared by two routes: by the reaction of Pd10(CO)12L6 with Me3NO in the presence of HOAc with ...

    E. G. Mednikov in Russian Chemical Bulletin (1993)

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    Article

    Redox reactions involving low-valence transition metal complexes: Palladium and platinum phosphinecarbonyl clusters in the synthesis of binuclear compounds

    The heterobinuclear complex, PtPdCl2(μ2-CO)(PPh3)3 was obtained by the redox addition of Pd4(CO)5(PPh3)4, and Pt4(CO)5(PPh3)4, to MCl2(PPh3)2, where M=Pd and Pt, as a single isomer containing the two PPh3 ligands...

    V. V. Bashilov, E. G. Mednikov… in Bulletin of the Academy of Sciences of the… (1987)

  4. No Access

    Article

    Synthesis of new palladium carbonyl phosphine halide clusters

    E. G. Mednikov, É. A. Grebenshchikova… in Bulletin of the Academy of Sciences of the… (1986)

  5. No Access

    Article

    Reaction of [Pt(CO)2]n with triarylphosphines

    1. The reaction of platinum dicarbonyl with triarylphosphines has afforded the clusters Pt3(CO)3(PAr3)4 and Pt5(...

    N. K. Eremenko, S. S. Kurasov… in Bulletin of the Academy of Sciences of the… (1986)

  6. No Access

    Article

    Interconversions of compounds of different nuclearity in the Pd(O)-CO-PPh3 system

    1. Interconversions of mono-, tri-, tetra-, and decanuclear palladium compounds take place in the zerovalent-pal...

    E. G. Mednikov, N. K. Eremenko in Bulletin of the Academy of Sciences of the… (1984)

  7. No Access

    Article

    Structure of the cluster Pt4(CO)5(PEt3)4 in solution

    V. F. Yudanov, N. K. Eremenko, E. G. Mednikov… in Journal of Structural Chemistry (1984)

  8. No Access

    Article

    Redox-demercuration by the cluster Pd10(CO)12(PBu3)6

    1. Organomercury compounds react with the cluster Pd10(CO)12(PBu3)6 to form mononuclearσ-complexes of palladium.

    V. V. Bashilov, E. G. Mednikov… in Bulletin of the Academy of Sciences of the… (1983)

  9. No Access

    Article

    Synthesis of Pt(0)-carbonyltrialkylphosphine clusters

    The reaction of platinum dicarbonyl with triethylphosphine gave Pt(0) clusters of composition: Pt5(CO)6(PEt3)4 and Pt4(CO)5(PEt3)4. Treatment of the latter with PEt3 gave the Pt3(CO)3(PEt3)4, cluster.

    N. K. Eremenko, E. G. Mednikov… in Bulletin of the Academy of Sciences of the… (1983)

  10. No Access

    Article

    Interconversions of clusters in the Pd(O), CO, P(n-Alk)3 system

    1. In a Pd(O), CO, P(n-Alk)3 system, using PBu3 as an example, interconversions of compounds Pd10(CO)14 (P Bu3)4

    E. G. Mednikov, N. K. Eremenko in Bulletin of the Academy of Sciences of the… (1982)

  11. No Access

    Article

    Synthesis of tetranuclear Pd(O) carbonyltrialkylphosphine clusters

    We obtained the tetranuclear Pd(0) carbonyltrialkylphosphine clusters of composition Pd4(CO)5(PAlk3)4, where Alk=n-Bu or Et.

    E. G. Mednikov, N. K. Eremenko in Bulletin of the Academy of Sciences of the… (1981)