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Article
Open AccessAn Expanded Model for the Pressure Effect in Metal Dusting of Mn-Containing Alloy 600 Based on Advanced Scale Characterization
Commercial alloy 600 was exposed to a metal dusting inducing gas mixture to investigate the effect of ambient and elevated pressures on the oxide scale formation behavior. The formed scales on this alloy were ...
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Article
Role of Elemental Segregation on the Oxidation Behavior of Additively Manufactured Alloy 625
This study presents the microstructure and oxidation behavior at 800°C in the air of Alloy 625 manufactured by conventional manufacturing and laser-assisted additive manufacturing (AM) processes: powder bed fu...
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Article
Do Mass Transport Kinetics Always Control Al2O3 Scale Growth? An Alternative Explanation for the Efficacy of the Reactive-Element Effect
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Chapter and Conference Paper
Effects of CO2 Cover Gas and Yttrium Additions on the Oxidation of AlMg Alloys
AlMg alloys are known to suffer from problematic that can result in significant dross formation and loss of Mg from the melt. Historically, beryllium has been used to minimize the as it forms a protective ...
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Article
Reinterpretation of Type II Hot Corrosion of Co-Base Alloys Incorporating Synergistic Fluxing
The components of gas-turbine engines operating in marine environments are highly susceptible to hot corrosion, which is typically classified as Type II (650–750 °C) and Type I (900–950 °C) hot-corrosion attac...
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Article
Promotion of the Al2O3-Scale Formation on Ni–Cr–Al Alloys via the Fluorine Effect
The halogen effect, which involves the surface enrichment of an alloy with a halogen element to result in improved oxidation resistance, was assessed using model Ni-based Ni–Cr–Al alloys. The alloys studied va...
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Article
Kinetic Study of the Competitive Growth Between θ-Al2O3 and α-Al2O3 During the Early Stages of Oxidation of β-(Ni,Pt)Al Bond Coat Systems: Effects of Low Oxygen Partial Pressure and Temperature
An oxidation study of β-(Ni,Pt)Al commercial bond coat systems was carried by means of TGA analysis during isothermal treatments at temperatures from 1273 K to 1423 K (1000 °C to 1150 °C). The effect of oxygen pa...
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Article
Alloying-Element Loss During High-Temperature Processing of a Nickel-Base Superalloy
The effect of exposure at temperatures commonly used for wrought processing/heat treatment of nickel-base superalloys on the loss of alloying elements at the free surface has been determined. For this purpose,...
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Article
The Effect of Microstructure on the Type II Hot Corrosion of Ni-Base MCrAlY Alloys
Alloys of compositions (in wt%) Ni–31.5Cr–11.5Al–0.6Y and Ni–20.9Co–19.2Cr–12.5Al–0.5Y–0.4Si–0.3Hf were prepared using three different processing routes and exposed to Type II (700 °C) hot corrosion conditions...
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Article
A combined map** process for the development of platinum-modified Ni-based superalloys
Heat-resistant Ni-based alloys have been used extensively for components in turbine engines for the past 50 years. Platinum group metal (PGM) alloying additions (i.e., platinum and iridium) have been found in ...
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Article
Sulfur Segregation at Al2O3/γ-Νi + γ′-Ni3Al Interfaces: Effects of Pt, Cr and Hf Additions
The interfacial chemistry that developed as a result Al2O3-scale growth on γ-Νi + γ′-Ni3Al alloys at 1150 °C was studied using scanning Auger microscopy after the oxide layer was scratched to spall under ultra-hi...
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Article
Structural Stability of Platinum-Group-Metal-Modified γ + γ′ Ni-Base Alloys
The structural and surface stabilities of two experimental γ-Ni+γ′-Ni3Al-base alloys containing Pt or Ir were investigated. These alloys are representative of alloys currently being developed to occupy a unique d...
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Article
Compositional factors affecting the establishment and maintenance of Al2O3 scales on Ni–Al–Pt systems
The beneficial role played by platinum addition in promoting the formation of a protective Al2O3 scale on representative γ′-Ni3Al+γ-Ni coating compositions during high-temperature oxidation is discussed. This ben...
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Article
Correlation between the Microstructure, Growth Mechanism, and Growth Kinetics of Alumina Scales on a FeCrAlY Alloy
The microstructural development of an alumina scale formed on a model FeCrAlY alloy during oxidation at 1200 °C was characterized for up to 2000 hours of growth. Quantitative scanning electron microscopy (SEM)...
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Article
Effects of Silicon on the Oxidation Behavior of Ni-Base Chromia-Forming Alloys
This paper compares and analyzes the oxidation behavior of Ni-base alloys with and without about 2.7 wt.% Si addition. The Ni-base alloys studied were of two types: cast model alloys or wrought commercial allo...
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Article
Scaling of Carbon Steel in Simulated Reheat Furnace Atmospheres
A low carbon steel was exposed to a series of laboratory-simulated combustion gases at temperatures of 700--1200°C. The gases corresponded to the products of burning natural gas with amounts of air varying fr...
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Article
Effects of Minor Elements on the Cyclic-Oxidation Behavior of Commercial Fe-Base 800-Series Alloys
The cyclic-oxidation behavior of commercial iron-base 800-series chromia-scale-forming alloys was studied at 1000°C in still air. Each thermal cycle consisted of one day at temperature followed by air cooling ...
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Article
Modelling gas motion in a rapid-compression machine
In this paper, a model which describes the behaviour of the pressure, density and temperature of a gas mixture in a rapid compression machine is developed and analyzed. The model consists of a coupled system o...
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Article
Rapid Growth of SiO2 Nanofibers on Silicon-Bearing Alloys
Exposure of Ni–Si and Co–Si alloys to Ar–CO2 and Ar–CO–CO2 gases at 1130°C led to rapid growth of crystalline SiO2 nanofibers from the alloy surfaces. The fibers were circular in cross section, of diameter about ...
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Article
Alloy design strategies for promoting protective oxide-scale formation
This article discusses general strategies for designing alloys to form protective oxide scales. Approaches based on classical alloyoxidation theories work reasonably well for single-phase alloys. However, high...