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Newly Designed Heterotrinuclear [Zn(II)2Ln(III)] Complexes Constructed from a Flexible C-Shaped Bis(salamo)-Based Ligand
AbstractA flexible octadentate C-shaped bis(salamo)-based ligand (H 4 L) with two different coordination environments, which can react with different...
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AN INVESTIGATION INTO THE IMPACT OF INTRODUCED THIOCYANATE ANIONS ON THE TRINUCLEAR Co(II) SALAMO-BASED COMPLEX
AbstractThe reaction of Co(OAc) 2 ·4H 2 O with multisite coordinated salamo-based ligand H 2 L containning six coordinating sites in presence of co-ligand...
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Construction of an Unprecedented Homodinuclear Copper(II) Salamo-Based Complex
AbstractA homo-dinuclear Cu(II) complex [Cu 2 (L) 2 ] with the stoichiometric ratio of Cu(II) : (L) 2– = 2 : 2 was synthesized by the reaction of the...
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SUPRAMOLECULAR ASSEMBLIES IN AN UNPRECEDENTED ASYMMETRIC SALAMO-BASED DINUCLEAR NICKEL(II) COMPLEX BEARING TWO DIFFERENT COORDINATION MODES
AbstractAn unprecedented dinuclear Ni(II) complex [{Ni 2 (L)(HL)(μ-OAc)(H 2 O)} 2 ]·3CH 3 CH 2 OH is successfully synthesized by the complexation of an...
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Experimental and Theoretical Studies of Two New Trinuclear Ni(II) Asymmetric Salamo-Based Complexes
AbstractTwo new trinuclear Ni(II) complexes, [{Ni(L)(DMF)(μ-OAc)} 2 Ni] ( 1 ) and [{Ni(L)(EtOH)(μ-OAc)} 2 Ni]·2CH 2 Cl 2 ( 2 ), have been successfully...
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Constructing Phenoxo-Bridged Heterobimetallic [Zn(II)2M(II)] (M = Sr and Ba) Salamo-Based Complexes
AbstractTwo new phenoxo-bridged heterobimetallic [Zn(II) 2 M(II)] (M = Sr and Ba) salamo-based complexes, [{Zn(L)(μ 2 -OAc)} 2 Sr]·0.33CH 3 OH·H 2 O ( 1 ) and...
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An investigation into luminescent phenoxo-bridged heterobimetallic copper(II)–calcium(II)/strontium(II)-based bis(salamo)-like complexes
Two luminescent hetero-trinuclear complexes [Cu 2 Ca(L)( µ 2 -NO 3 ) 2 ] ( 1 ) and [{Cu 2 Sr(L)( µ 2 -NO 3 )( ƞ 2 -NO 3 )} 2 ]·2EtOH·H 2 O ( 2 ) have been prepared by a flexible...
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A NOVEL TETRANUCLEAR NICKEL(II) SALAMO-BASED COMPLEX ADOPTING TWO OPEN CUBIC STRUCTURES: SYNTHESIS, CHRACTERIZATION, DFT CALCULATION, HIRSHFELD ANALYSIS, AND FLUORESCENT PROPERTIES
AbstractA novel tetranuclear Ni(II) complex [Ni 4 (L) 2 (N 3 ) 4 Cl(MeOH) 3 ]·CH 3 COCH 3 is synthesized via a symmetrical salamo-based ligand H 2 L, NiCl 2 ·6H 2 O,...
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INSIGHT INTO FLUORESCENT PROPERTIES, DFT AND HIRSHFELD ANALYSES OF A NEWLY SYNTHESIZED AND STRUCTURALLY NOVEL TRINUCLEAR COPPER(II) SALAMO-BASED COMPLEX INVOLVING PHENOXO-O BRIDGED COORDINATION
AbstractA novel trinuclear Cu(II) (Cu 2+ :(L) 3− = 3:2) complex derived from a newly designed pentadentate salamo-based ligand (H 3 L), namely [Cu 3 (L) 2 (CH
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Insight into Crystal Structures, Hirshfeld Surfaces and Fluorescent Properties of Multinuclear Co(II) and Ni(II) Salamo-Based Complexes Involving Lone Pair π-Interactions
AbstractTwo multi-nuclear Co(II) and Ni(II) complexes, [{Co 3 (L) 2 (EtOH) 2 (μ-OAc) 2 } 2 ]·2CH 3 CH 2 OH· CH 2 Cl 2 ·CHCl 3 ·CH 3 CN ( 1 ) and [{Ni 3 (L) 2 (EtOH) 2 (μ-OAc) 2 } 2 ]·3CH...
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Insight into new mono- and tri-nuclear nickel(II)-based complexes supported by structural variation of salamo-like ligands
New mono- and tri-nuclear Ni(II)-based complexes, [Ni(L 1 ) 2 ] ( 1 ) and [{Ni(L 2 )(DMF)( μ -OAc)} 2 Ni]·2EtOH·2CH 2 Cl 2 ( 2 ), supported by half-salamo- and...
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Structurally novel bi-nuclear cobalt(III) complex self-assembled by a single-armed salamo-like ligand
A structurally novel bi-nuclear Co(III) complex ([Co 2 (L) 2 (H 2 O) 2 ]) was prepared by the reaction of a single-armed salamo-like ligand H 3 L and Co(II)...
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Structural Characterization, Hirshfeld Analyses, Fluorescence, and Catalytic Oxidase Properties of New Cu(II) and Co(II) Halogen-Substituted Salamo-Based Complexes
AbstractTwo mononuclear Cu(II) and Co(II) halogen-substituted salamo-based complexes of the formulas [Cu(L)] and [Co(L)(H 2 O) 2 ] have...
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AN NOVEL ANTIBACTERIAL ACTIVE [CuII–GdIII] COMPLEX CONSTRUCTED FROM AN ASYMMETRIC SALAMO-BASED LIGAND: SYNTHESIS AND STRUCTURAL CHARACTERIZATION
AbstractIn the present study, we describe a reaction of Cu(OAc) 2· H 2 O and Gd(NO 3 ) 3· 6H 2 O with equimolar amounts of the asymmetric salamo-type ligand...
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Synthesis, Crystal Structure, Fluorescence Property, and Theoretical Investigation of Counteranion-Introduced Ni(II) Complex with Pyridine-Appended Half-Salamo-Like Ligand
AbstractA new counteranion-introduced Ni(II) complex, [Ni(L)(NCS)(EtOH)] supported by a pyridine-appended half-salamo-like ligand HL has been...
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A Bis(Salamo)-Based Fluorogenic Sensor for Highly Selective and Sequential Recognition of Cu2+ and B4O72− Ions in Semi-Aqueous Medium
A new type of multifunctional bis(salamo)-based fluorogenic sensor H 2 BS was designed and synthesized. Under the action of V DMF : V H2O = 9: 1, the...
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Three supramolecular trinuclear nickel(II) complexes based on Salamo-type chelating ligand: syntheses, crystal structures, solvent effect, Hirshfeld surface analysis and DFT calculation
Three Ni(II) complexes {[NiL(μ-OAc)(CH 3 CH 2 OH)] 2 Ni} ( 1 ), {[NiL(μ-OAc)(CH 3 OH)] 2 Ni]·2CH 2 Cl 2 ·2CH 3 OH ( 2 ) and {[NiL(μ-OAc)(CH 3 OH)] 2 Ni}·1.5CH 3 OH ( 3 ) based...
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AN EXPLORATION OF STRUCTURALLY CHARACTERIZED HETERO-TRINUCLEAR [Cu(II)2Ca(II)] FLEXIBLE-BIS(SALAMO)-TYPE COMPLEX
AbstractA new bis(salamo)-type ligand has been designed and synthesized, and its hetero-trinuclear [Cu(II) 2 Ca(II)] complex has been successfully...
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Synthesis and Crystal Structure of Zero-Dimensional Trinuclear Ni(II) Salamo-Type Complex Involving a Variety of Interactions
AbstractA new trinuclear nickel(II) complex, [{NiL(EtOH)(μ-OAc)} 2 Ni]·2CH 3 CH 2 OH were synthesized via the reaction of a salamo-type ligand H 2 L with...
