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Structural Characterization, Hirshfeld Analyses, Fluorescence, and Catalytic Oxidase Properties of New Cu(II) and Co(II) Halogen-Substituted Salamo-Based Complexes

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Abstract

Two mononuclear Cu(II) and Co(II) halogen-substituted salamo-based complexes of the formulas [Cu(L)] and [Co(L)(H2O)2] have been synthesized and characterized by elemental analyses, FT-IR and UV-Vis absorption spectra, and X-ray crystallography. The Cu(II) complex has crystallized in the monoclinic system, space group P21/n with Cu(II) atom located in the N2O2 cavity. In the Co(II) complex, the center Co(II) atom has exhibited a slightly distorted octahedral geometry with halogen-substituted salamo-based bisoxime forming the basal N2O2 coordination plane and two oxygen atoms of two coordinated water molecules in the axial positions. Non-covalent interactions like hydrogen bonding and π···π stacking interactions are operative in construction of supramolecular architectures. The crystal structures and supramolecular features of the complexes have been discussed in details. Hirshfeld surfaces analyses has indicated stability of both complexes. The Cu(II) complex has demonstrated excellent bio-inspired catalytic properties towards oxidative coupling of 2-AP in MeCN medium. Fluorescence properties of H2L and its Cu(II) and Co(II) complexes have also been discussed.

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Notes

  1. Crystallographic data have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication, no. CCDC 2039525 and 2039524 contain the supplementary crystallographic data for the Cu(II) and Co(II) complexes. These data can be obtained free of charge via http://www.ccdc.cam.ac.uk/conts/retrieving.html, or from the Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB2 1EZ, UK; fax: (+44) 1223-336-033; or e-mail: deposit@ccdc.cam.ac.uk.

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Funding

This work was supported by the National Natural Science Foundation of China (21761018), Science and Technology Program of Gansu Province (18YF1GA057) and the Program for Excellent Team of Scientific Research in Lanzhou Jiaotong University (201706), three of which are gratefully acknowledged. Computations were done using National Supercomputing Center in Shenzhen, P. R. China.

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  1. School of Chemical and Biological Engineering, Lanzhou Jiaotong University , 730070, Gansu, Lanzhou, China

    S.-Z. Guo, Y.-J. Li, S.-S. Feng & W.-K. Dong

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Correspondence to W.-K. Dong.

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Guo, SZ., Li, YJ., Feng, SS. et al. Structural Characterization, Hirshfeld Analyses, Fluorescence, and Catalytic Oxidase Properties of New Cu(II) and Co(II) Halogen-Substituted Salamo-Based Complexes. Russ J Gen Chem 90, 2435–2443 (2020). https://doi.org/10.1134/S107036322012035X

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