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DABCO-based ionic salts: synthesis, characterization, and application as organocatalysts in asymmetric reduction reactions
GUMBOS (group of uniform materials based on organic salts) are highly functional and tunable organic ionic materials that exhibit a solid state at...
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New organocatalysts derived from tetrahydropapaverine for asymmetric aldol reaction
AbstractSynthesis of prolinamide derivatives of ( R )-tetrahydropapaverine as mono-, di- and tripeptide is reported. ( R )-Tetrahydropapaverine-prolinami...
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Two New Diastereometric Dihydroisoquinolinium Salts as Organocatalysts for Asymmetric Epoxidation of Alkenes
AbstractTwo new diastereomeric dihydroisoquinoline-derived iminium salts containing an asymmetric center in the exocyclic substituent at the nitrogen...
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Novel C2-symmetric phenylglycine derivatives as organocatalysts of the Michael reaction between nitroalkenes and ketones
A comprehensive study of the activity of the amide-type organocatalysts based on ( R )- and ( S )-phenylglycine and 1,2-di(2-pyridyl)-1,2-diaminoethane...
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Organocatalytic Reductive Functionalization of Carbon Dioxide
The catalytic transformation of carbon dioxide (CO2) into value-added chemicals and high-value fuels is the most promising strategy to mitigate the...
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Computational Study on the Route of Cooperative Organocatalysis Utilizing Thiourea and Halogen Bond Donor Mixture
AbstractA computational analysis of possible routes of cooperative catalysis involving hydrogen bond donating thiourea and halogen bond donating...
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Preparation of high-molecular-weight polylactide by ring-opening polymerization of l-lactide using base/bisurea binary organocatalyst
Despite the advantages of organocatalysts, the preparation of high-molecular-weight polylactide using organocatalysts remains as a challenge probably...
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Organocatalysis in 1,3-Dipolar Cycloaddition Reactions (A Review)
AbstractOne of the promising directions in 1,3-dipolar cycloaddition is the implementation of these reactions under organocatalysis conditions, which...
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Isoselective Ring-opening Polymerization of Racemic Lactide Catalyzed by N-heterocyclic Olefin/(Thio)urea Organocatalysts
The isoselective ring-opening polymerization of racemic lactide was achieved by combining N -heterocyclic olefin (NHO) with mono(thio)ureas or...
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Ultra-high-throughput map** of the chemical space of asymmetric catalysis enables accelerated reaction discovery
The discovery of highly enantioselective catalysts and elucidating their generality face great challenges due to the complex multidimensional...
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Correction to: Macrocycles in dual role: ancillary ligands in metal complexes and organocatalysts for the ring‑opening polymerization of lactide
A correction to this paper has been published: https://doi.org/10.1007/s10847-021-01060-y
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Performance studies of CO2 transformation to methanol by zwitterionic indenylammonium derivatives as a new class of carbon-centered organocatalysts
Theoretical studies of carbon-centered organocatalysts for CO 2 activation and mechanism studies for its conversion to methanol are the purposes of...
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Precision in stereochemistry: the integral role of catalytic asymmetric Biginelli reaction in crafting enantiomerically pure dihydropyrimidinones
One well-known multicomponent reaction that is helpful in the synthesis of dihydropyrimidinones (DHPMs), important molecules in organic synthesis and...
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Organocatalytic Diastereoselective Synthesis of Spiro[3-azabicyclo[3.1.0]hexanes] via 1,3-Dipolar Cycloaddition of Azomethine Ylides with Cyclopropenes
AbstractA three-component organocatalytic reaction of 1,3-dipolar cycloaddition between the in situ generated azomethine ylides and 3-substituted...
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Real-time 31P NMR reveals different gradient strengths in polyphosphoester copolymers as potential MRI-traceable nanomaterials
Polyphosphoesters (PPEs) are used in tissue engineering and drug delivery, as polyelectrolytes, and flame-retardants. Mostly polyphosphates have been...
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Squaramide-Based Catalysts in Organic Synthesis (A Review)
AbstractThe review considers works published over the past 5 years on the synthesis, modifications, and application of chiral catalysts based on...
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Macrocycles in dual role: ancillary ligands in metal complexes and organocatalysts for the ring-opening polymerization of lactide
In the twenty-first century, one of the central focus of polymer research in academia and industries is directed towards the design of...
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Dual cooperative organocatalysts for one-pot synthesis of polyester-polythiocarbonate block copolymers from multiple monomers
The sequential arrangement of multiple monomer units in a polymer chain remains a major challenge in synthetic chemistry. Here we describe a...