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Spin Crossover—An Overall Perspective
In this chapter an outline is presented of the principal features of electronic spin crossover. The development of the subject is traced and the...
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Iron(III) Spin Crossover Compounds
In this chapter, selected results obtained so far on Fe(III) spin crossover compounds are summarized and discussed. Fe(III) spin...
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Light-Induced Spin Crossover and the High-Spin→Low-Spin Relaxation
The discovery of a light-induced spin transition at cryogenic temperatures in a series of iron(II) spin-crossover compounds in 1984 has had an...
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Towards Spin Crossover Applications
In this chapter we attempt to review the potential for the application of the spin crossover (SCO) phenomenon in various domains, such as molecular...
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Heat Capacity Studies of Spin Crossover Systems
As the spin crossover phenomena occurring in Oh symmetry involve a transfer of electrons between the eg and t2g orbitals, the metal-to-ligand bond...
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Spin Crossover in Pyrazolylborate and Pyrazolylmethane Complexes
The electronic spin-state crossover observed upon cooling and at high-pressure in the iron(II) and cobalt(II) complexes formed with the HB(pz)3...
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Elastic Interaction in Spin-Crossover Compounds
The derivation of the Gibbs free energy of a spin crossover system in terms of the mean field approximation of the interacting molecules involves an...
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Special Classes of Iron(II) Azole Spin Crossover Compounds
In this chapter, selected results obtained so far on Fe(II) spin crossover compounds of 1,2,4-triazole, isoxazole and tetrazole derivatives are...
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Iron(II) Spin Crossover Systems with Multidentate Ligands
This chapter focuses on the synthesis and characterization of iron(II) spin crossover compounds in which one of the ligands is multidentate. Here we...
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Density Functional Theory Calculations for Spin Crossover Complexes
Density functional theory (DFT) provides a theoretical framework for efficient and fairly accurate calculations of the electronic...
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Time-Resolved Relaxation Studies of Spin Crossover Systems in Solution
This chapter focuses on the kinetics of spin-state relaxation, primarily in iron(II) complexes in solution. Initial work carried out during the 1970s...
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Bipyrimidine-Bridged Dinuclear Iron(II) Spin Crossover Compounds
This review reports on the study of the interplay between magnetic coupling and spin transition in 2,2′-bipyrimidine (bpym)-bridged iron(II)...
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Isokinetic and Isoequilibrium Relationships in Spin Crossover Systems
A thorough statistical mechanical analysis of sources of variations and correlations in ΔE 0 and ΔS 0 of spin crossover...
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The Role of Molecular Vibrations in the Spin Crossover Phenomenon
The prominent role of intra- and inter-molecular vibrations in the spin crossover phenomenon is outlined, based on the results...
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Pressure Effect Studies on Spin Crossover and Valence Tautomeric Systems
In the present review chapter we discuss the results of investigations of the influence of hydrostatic pressure (up to 1.2 GPa) on the spin...
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Spin Crossover in Cobalt(II) Systems
Cobalt(II), a d 7 ion, can exist in a low spin doublet state or a high spin quartet state. Both spin-state configurations are known in...
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Structural Aspects of Spin Crossover. Example of the [FeIILn(NCS)2] Complexes
The interplay between the spin crossover and the structural properties of the complexes in the solid state is still under investigation. In...
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Illuminating spin-crossover octanuclear metal-organic cages
Spin-crossover (SCO) materials that reversibly switch between high- and low-spin states have potential for the storage of spin state-relative...
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Cooperativity in Spin Crossover Systems: Memory, Magnetism and Microporosity
This review deals with spin crossover effects in small polynuclear clusters, particularly dinuclear species, and in extended network...
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Spin Crossover in Iron(II) Tris(diimine) and Bis(terimine) Systems
Tris(diimine) and bis(terimine) iron(II) complex salts constitute one of the major classes of spin crossover systems. Both electronic and structural...