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Spin Crossover in Iron(II) Tris(diimine) and Bis(terimine) Systems

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Spin Crossover in Transition Metal Compounds I

Part of the book series: Topics in Current Chemistry ((TOPCURRCHEM,volume 233))

Abstract

Tris(diimine) and bis(terimine) iron(II) complex salts constitute one of the major classes of spin crossover systems. Both electronic and structural modifications can be made so as to bring the ligand field of the parent imines, 2,2′-bipyridine, 1,10-phenanthroline and 2,2′:6′,2″- terpyridine into the crossover range with some degree of confidence. The resulting imine systems are considered and classified according to their structural types. Among the many crossover systems in this class are several which display a high degree of cooperativity in the solid state, and the incorporation of hydrogen-bonding sites into the ligand structure also strongly influences many solid-state properties

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Acknowledgements

The contributions from my students and colleagues together with support of the University of New South Wales, the Australian Research Council and the Alexander von Humboldt Stiftung are gratefully acknowledged. The rewarding collaborations with Professors E. König and G. Ritter at Erlangen, and Professor P. Gütlich and his group at Mainz have stimulated my continuing fascination for the spin crossover phenomenon.

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  1. School of Chemical Sciences, University of New South Wales, 2052, Sydney, NSW, Australia

    Harold A. Goodwin

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P. Gütlich H.A. Goodwin

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Goodwin, H.A. Spin Crossover in Iron(II) Tris(diimine) and Bis(terimine) Systems. In: Gütlich, P., Goodwin, H. (eds) Spin Crossover in Transition Metal Compounds I. Topics in Current Chemistry, vol 233. Springer, Berlin, Heidelberg. https://doi.org/10.1007/b13529

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  • DOI: https://doi.org/10.1007/b13529

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-540-40394-4

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