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Preparation of optical nano sensor for rapid detection of Fe(III) using phenyl isothiocyanate functionalized SBA-15
The present study focuses on the synthesis of a mesoporous silica compound functionalized with phenyl isothiocyanate (SBA-15-PITC) for the...
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Design, spectral, molecular modeling, antimitotic, analytical and mechanism studies of phenyl isothiocyanate Girard's T derived metal complexes
The ligand N-{[(phenyl amino) thioxomethyl] hydrazino carbonyl methyl} trimethyl ammonium chloride (PTHAC) was prepared by the refluxing phenyl...
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A novel synthesis of isothiocyanates from amines and phenyl isothiocyanate via replacement reaction
A new efficient method for the synthesis of isothiocyanates has been developed via the replacement reaction of phenyl isothiocyanate and the...
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Molecular Description and Hirshfeld Analysis of the (–)-S-1-[2-(Benzenesulfonamido)-3-Phenylpropanoyl]-4-[(4-Chloro)Phenyl]Thiosemicarbazide
Abstract(–)-( S )-1-[2-(Benzenesulfonamido)-3-phenylpropanoyl]-4-[(4-chloro)phenyl]thiosemicarb-azide was synthesized by condensing (+)-( S )-2-(benzenes...
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Docking, DFT, and structural study of N-((1,5-dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-yl)carbamothioyl)benzamide
In the current work, we report the synthesis and characterization of...
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Reactions of Pyridoxal Derivatives with Phenyl Iso(thio)cyanates
AbstractThe reaction of phenyl isocyanate with pyridoxal is carried out with the participation of hydroxymethyl and phenolic groups with the...
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Synthesis, physical properties, and computational biological activity of N-{[(3(4)-halophenyl)amino]carbonothioyl}adamantane-1-carboxamides
Thioureas containing halogen- and dihalogen-substituted phenyl fragments were obtained based on adamantan-1-ylcarbonyl isothiocyanate in up to 76–94%...
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Synthesis and Some Transformations of 4-Oxo-7-phenyl-3,4,5,6,7,8-hexahydro[1]benzothieno[2,3-d]pyrimidine-7-carbonitrile
AbstractThe condensation of ethyl 2-amino-6-cyano-6-phenyl-4,5,6,7-tetrahydro-1-benzothiophene-3-carboxylate with formamide gave...
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Regioselective three-component synthesis and theoretical calculations of new alkane-linked bis(thiazol-2(3H)-imine) hybrids: a DFT-based FMO and local reactivity indices
A three-component approach was conducted to adeptly prepare a new series of ( Z )-bis( N -phenylthiazol-2(3 H )-imines. The newly synthesized compounds...
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Synthesis of Schiff Bases and Isoindolyl- and Thiazolyl-Substituted Quinolines from 6-Amino-2-methylquinolin-4-ol
AbstractReactions of 6-amino-2-methylquinolin-4-ol with salicylaldehyde, phthalic anhydride, phenyl isothiocyanate, and ammonium thiocyanate afforded...
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Design, synthesis, characterization, and docking studies of hiherto unkown chlorinated thiazolidine, thiophene, and 2-iminochromene derivatives as protein-like protease inhibitors
The present work details the synthesis of several intriguing nitrogenous heterocycles utilizing a cyano- N -aryl-acetamide-reagent, notably chlorinated...
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Novel synthetic routes for Pyrimidine, Pyridine and Pyrazole Derivatives and Their Antibacterial Evaluation
AbstractAn efficient and facile protocol for the synthesis of pyrimidine, pyridine and pyrazole ring systems was reported, Reaction of isothiocyanate...
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A SUPRAMOLECULAR STRUCTURE OF PHOSPHORYLATED
N -PHENYL-1,2,4-TRIAZOLE- 3-THIONE AND ITS CRYSTAL SOLVATEAbstractA comparative analysis of the molecular and crystal structures is performed for 5-[(diphenylphosphoryl) methyl]-4-phenyl-2,4-dihydro-3 H -1,2,4...
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Synthesis and Some Transformations of 5-(1,4-Benzodioxan-2-yl)-4-phenyl-4H-1,2,4-triazole-3-thiol
AbstractThe title compound was synthesized by reaction of 1,4-benzodioxane-2-carbohydrazide with phenyl isothiocyanate, followed by cyclization of...
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Clean and Green Synthesis of Organic Isothiocyanates Using Zinc Peroxide as Desulfurizing Agent and Their Antimicrobial Activity
AbstractA clean, green, and efficient procedure has been developed for the synthesis of organic isothiocyanates using zinc peroxide as a...
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Synthesis and reactivity of the complexes [(dpp-bian)SiCl2] and [(dpp-bian)Si{FeCp(CO)}2(μ-CO)] (dpp-bian is 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene)
The complex [(dpp-bian)SiCl 2 ] ( 1 ) was synthesized by the reaction of the free 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene (dpp-bian) ligand...
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Antioxidant Activity of Edible Isothiocyanates
Naturally occurring isothiocyanates (ITCs), products of hydrolysis of glucosinolates (GSLs), attract great attention due to their well-defined... -
Fano Resonance in Plasmonic Crystals Enables High-Sensitive Arsenite Detection
Fano resonance exhibiting characteristic asymmetric spectral line shape is a universal phenomenon, observed in diverse systems and is widely studied...
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Novel Triazole-, Oxadiazole-, and Pyrazole-Nicotinonitrile Hybrids: Synthesis, DFT Study, Molecular Docking, and Antimicrobial Activity
AbstractThe present study is devoted to functionalization of ethyl 2-{[3-cyano-6-(4-cyanophenyl)-4-(2,4-dichlorophenyl)pyridin-2-yl]oxy}acetate ( 1 )...