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Reactions of Pyridoxal Derivatives with Phenyl Iso(thio)cyanates

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Abstract

The reaction of phenyl isocyanate with pyridoxal is carried out with the participation of hydroxymethyl and phenolic groups with the formation of dicarbamate derivatives. The reactions of pyridoxal azomethines with phenyl isocyanate, depending on the structure and the ratio of the starting reagents, lead to the formation of mono-, di- or tricarbamate derivatives. The product of addition of azomethine pyridoxal to phenyl isocyanate with the participation of a hydroxymethyl group was obtained.

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ACKNOWLEDGMENTS

The authors are grateful to the Collective Spectro-Analytical Center for Physicochemical Research of the Structure, Properties and Composition of Substances and Materials of the Federal Research Center “Kazan Scientific Center of the Russian Academy of Sciences” for technical support.

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Authors and Affiliations

  1. Arbuzov Institute of Organic and Physical Chemistry, Federal Research Center “Kazan Scientific Center of the Russian Academy of Sciences”, 420088, Kazan, Russia

    L. K. Kibardina, A. V. Trifonov, A. B. Dobrynin, A. R. Burilov & M. A. Pudovik

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  1. L. K. Kibardina
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  2. A. V. Trifonov
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  3. A. B. Dobrynin
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  4. A. R. Burilov
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  5. M. A. Pudovik
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Corresponding author

Correspondence to A. V. Trifonov.

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Additional information

Translated from Zhurnal Obshchei Khimii, 2021, Vol. 91, No. 8, pp. 1151–1158 https://doi.org/10.31857/S0044460X21080011.

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Kibardina, L.K., Trifonov, A.V., Dobrynin, A.B. et al. Reactions of Pyridoxal Derivatives with Phenyl Iso(thio)cyanates. Russ J Gen Chem 91, 1431–1437 (2021). https://doi.org/10.1134/S1070363221080016

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