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Ketoreductase-assisted synthesis of chiral selective tert-butyl{5-[(4-cyanophenyl)(hydroxy)methyl]-2-fluorophenyl}carbamate: process minutiae, optimization and characterization
Ketoreductases capable of performing chiral selective reduction in tert-butyl[5-(4-cyanobenzoyl)-2-fluorophenyl]carbamate to...
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Synthesis of tert-Butyl N-(2-{[({1-Methyl-5-[(triphenylmethyl)amino]-1H-pyrazol-4-yl}amino)carbonyl]amino}ethyl)carbamate
AbstractAn important intermediate product in the synthesis of ceftolozane, tert -butyl N -(2-{[({1-methyl-5-[(triphenylmethyl)amino]-1 H -pyrazol-4-yl}am...
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Alkaline Hydrolysis of Paraoxon in Micellar Solutions of Carbamate Surfactant
AbstractThe hydrolytic decomposition of the organophosphorus ecotoxicant paraoxon in alkaline micellar solutions of a cationic surfactant with a...
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Synthesis and Some Transformations of New Acetophenone Derivatives Containing a Carbamate Moiety
AbstractThe acylation of methyl phenylcarbamate, 2-(morpholin-4-yl)ethyl phenylcarbamate, and 2-(pyridin-2-yl)ethyl phenylcarbamate with acetic...
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1,3-Dipolar Cycloaddition of Nitrones to Methyl {4-[(2E)-3-(4-Methoxyphenyl)prop-2-enoyl]phenyl}carbamate
Abstract1,3-Dipolar cycloaddition of nitrones to methyl {4-[(2 E )-3-(4-methoxyphenyl)prop-2-enoyl]phenyl}carbamate regioselectively afforded the...
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Synthesis by carbonate aminolysis and chiral recognition ability of cellulose 2,3-bis(3,5-dimethylphenyl carbamate)-6-(α-phenylethyl carbamate) selectors
AbstractNovel chiral selectors based on cellulose 2,3- bis (3,5-dimethylphenyl carbamate)-6-( α -phenylethyl carbamate) were regioselectively...
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Insights into the HO· and HOO· radical scavenging activity of aryl carbamate derivative: a computational mechanistic and kinetic investigation
Aryl carbamates exhibit significant utility due to their diverse range of biological activities, including anticancer, antituberculosis, and...
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Design and synthesis of novel totarol derivatives bearing carbamate moiety as potential fungicides
A series of totarol derivatives were synthesized by introducing the carbamate moiety into the molecular structure, and their antifungal effects...
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Aggregation Behavior and Catalytic Action of Carbamate-Bearing Surfactants in Aqueous Solutions
AbstractThe aggregation behavior of new cationic hexadecyl surfactants with one or two alkylcarbamate fragments in the head group in water was...
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Optimization of the regioselective synthesis of mixed cellulose 3,5-dimethylphenyl and α-phenylethyl carbamate selectors as separation phases for chiral HPLC
Regioselective tritylation and carbonate aminolysis were employed in this work to synthesize cellulose 2,3- bis (3,5-dimethylphenyl carbamate)-6-( α -phen...
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Rapid detection of carbamate nerve agent analogues using dually functionalized gold nanoclusters
Carbamate nerve agents (CMNAs) are a type of lethal cholinesterase inhibitor with one or more quaternary amine centres and aromatic rings. CMNAs have...
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Removal of two carbamate pesticides from aqueous solutions using an adsorbent material based on poly(vinyl alcohol) and malic acid hydrogels
This study describes through Molecular dynamics simulations the interactions between two carbamate pesticides, Carbofuran (CFN) and Methomyl (MML),...
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Enantioselective membranes prepared by electrospinning of cellulose tris(3,5-dimethylphenyl carbamate) having various degrees of polymerization: effect of the DP on the morphology
Cellulose phenyl carbamates such as cellulose tris (3,5-dimethylphenyl carbamate) (CDMPC) are known to act as chiral selectors when they are coated or...
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Tetrameric self-assembling of water-lean solvents enables carbamate anhydride-based CO2 capture chemistry
Carbon capture, utilization and storage is a key yet cost-intensive technology for the fight against climate change. Single-component water-lean...
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Molecularly imprinted bulk and solgel optosensing based on biomass carbon dots derived from watermelon peel for detection of ethyl carbamate in alcoholic beverages
Biomass carbon dots synthesized by biological waste conform to the trend of ecological environmental protection and the requirements of green...
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Aminolysis of O-methyl-N-methylcarbamate as a model for the production of polyureas. a DFT study
Model reaction of the formation of aliphatic polyureas—the reaction of O-methyl-N-methylcarbamate with methylamine was studied at the M06 and B3LYP...
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Fabrication and characterization of ZrO2 and ZrO2/SiO2 catalysts and their application in the synthesis of methyl N-phenyl carbamate: a study of the reaction mechanism by using in situ FT-IR spectroscopy
The reaction of dimethyl carbonate (DMC) and aniline for the synthesis of methyl N-phenyl carbamate (MPC) over ZrO 2 /SiO 2 catalyst was investigated....
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An oxidative expansion mechanism of isatin-derived imines
Sodium borohydride induces the oxidative expansion of the imine derived from isatin and phenylethylamine to form 3-phenethylquinazoline-2,4(1 H ,3 H )-dio...
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Montmorillonite K30 Supported Tungstophosphoric Acid as an Efficient Catalyst for Condensation Reaction of Methyl N-phenylcarbamate for Generating Diurethane
Methylene diphenyl-4,4′-dicarbamate (MDC) was prepared via condensation reaction of methyl N -phenyl carbamate (MPC) and formaldehyde (HCHO) over...
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Core–shell Ag-dual template molecularly imprinted composite for detection of carbamate pesticide residues
Carbamate pesticides are popularly used in agriculture due to their relatively low toxicity and their more degradable nature compared to...
