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Defluorination Techniques: Past, Present and Future Prospective
Fluoride ions are commonly found in minerals like mica, fluorapatite, muscovite, topaz, biotite, sellaite, cryolite, muscovite, and fluorspar....
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Substantial defluorination of polychlorofluorocarboxylic acids triggered by anaerobic microbial hydrolytic dechlorination
Chlorinated polyfluorocarboxylic acids (Cl-PFCAs) derived from the widely used chlorotrifluoroethylene oligomers and polymers may enter and influence...
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Photochemical degradation pathways and near-complete defluorination of chlorinated polyfluoroalkyl substances
Chlorinated polyfluoroalkyl substances (Cl x –PFAS) are an emerging class of pollutants worldwide. Here we demonstrate near-complete defluorination...
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The Defluorination of SiF4 on Si (1 1 1) Surfaces: a Density Functional Theory Study
In this paper, the defluorination of SiF 4 on Si (1 1 1) surface are studied by adopting density functional theory calculation. SiF 4 defluorination on...
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Selective Defluorination Induced by Photoactive Metallocomplexes
As the importance of partially fluorinated compounds continues to surface in the agricultural, pharmaceutical, and material fields, new synthetic... -
Oxidative defluorination of fluorinated ethylene propylene polymer in moist Cl2 at a low temperature: A mechanistic insight
Defluorination of fluorinated ethylenepropylene (FEP) occurred by reaction with moist Cl 2 in the presence of HCl and O 2 at -20 °C is described. White...
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Studying the Possibility for Defluorination of Calcium and Rare-Earth Fluorides by Ammonium Sulfate
AbstractThe processes of solid-phase interaction between calcium and rare-earth fluorides and ammonium sulfate have been studied. Based on...
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Near-complete destruction of PFAS in aqueous film-forming foam by integrated photo-electrochemical processes
Per- and polyfluoroalkyl substances (PFAS) are highly recalcitrant pollutants in the water environment worldwide. Aqueous film-forming foam (AFFF)...
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Thermally treated sludge obtained from a coagulation–flocculation water treatment process as a low-cost and eco-friendly adsorbent for water defluorination
The excess of fluoride ions in potable water is an important public health problem. This study has evaluated the thermal treatment process of a...
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Enzymatic defluorination of fluorinated compounds
Fluorine-containing compounds are widely used because they have properties required in textiles and coatings for electronic, automotive, and outdoor...
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New insights and reaction mechanisms on ZrO2 (110) surface enhanced catalytic hydrolysis of CFC-12: a density functional theory study
ContextFreon, a greenhouse gas that contributes to the depletion of the ozone layer, has been the subject of investigation in this study. The...
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Aryl dechlorination and defluorination with an organic super-photoreductant
Direct excitation of the commercially available super-electron donor tetrakis(dimethylamino)ethylene (TDAE) with light-emitting diodes at 440 or 390...
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Influence Mechanism of O2/H2O Adsorption on Cu(111) Surface on SF6 Overheating Failure Decomposition
In gas-insulated equipment, the decomposition of SF 6 is closely related to the residual traces of O 2 and H 2 O in the equipment. However, the...
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Development of a Completely New PFOS Alternative with Lower Surface Tension for Minimizing the Environmental Burden
Improving the technical performance of related industrial products is an efficient strategy to reducing the application quantities and environmental...
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Integrated Technology for Processing of Apatite Concentrate
AbstractA technology is proposed for processing of apatite concentrates by decomposition by phosphoric acid at 20°C in the presence of a sulfonic...
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Synthesis of Organofluorine Compounds
This chapter describes representative examples of the photocatalytic fluorination and di- and trifluoromethylation of organic compounds mediated by... -
Density functional theory investigation on aqueous degradation mechanism of norfloxacin initiated by hydroxyl radical
Aqueous degradation mechanism of norfloxacin (NOR) initiated by hydroxyl radical ( • OH) was investigated employing density functional theory (DFT)...
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What happens to the interfacial reaction between fluoropolymer and nano aluminum below 1000 ℃?
The interfacial reaction of nano-aluminum (nAl) and fluoropolymer was evaluated using nAl@Viton composite under slow and rapid heating rates. The...
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Ultrasonic-assisted synthesis of Populus alba activated carbon for water defluorination: Application for real wastewater
Efficient activated carbon was ultrasonically synthesized from the Populus alba tree, and fluoride ions were removed from samples of synthetic and...