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Synthesis and structure of antimony complexes [Ph3AmP]
2 + [Sb2I8 · 2DMSO]2−, [Ph3PrP]2 + [Sb2I8 · C4H8O2]2−, and [(HOCH2CH2)3NH]4 + [Sb4I16]4−The reaction of equimolar amounts of triphenylamyl- and triphenylpropylphosphonium iodides and triethanolammonium iodide with antimony iodide in...
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Solid Base Catalysts for Specific Subjects
Fatty acid methyl esters derived from vegetable oil are considered to be a potential diesel fuel extender known as biodiesel. Methyl esters of fatty...
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Homocatenation of Metal and Metalloid Main Group Elements
Interest in poly(diorgano)silanes, catenated silicon compounds and heavier element analogues of alkanes has derived largely from their 1-dimensional...
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Mechanism of ethylene hydroformylation on platinum complexes with hydrophosphoryl ligands: a DFT study
The mechanism of ethylene hydroformylation on model organoplatinum hydrides [(R 2 PO) 2 H]Pt(PR 3 )(H)] (R = H, Me, CF 3 ) was studied within the framework...
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Actinide Structural Chemistry
This chapter focuses on the solid state structural chemistry of actinide materials as determined by single–crystal X–ray diffraction, single–crystal...
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Uranium*
Uranium compounds have been used as colorants since Roman times (Caley, 1948). Uranium was discovered as a chemical element in a pitchblende specimen...
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Spiro- and Tricyclic Phosphoranes with Six- and Higher-Membered Rings
This article presents developments in synthetic and structural aspects of tetra-, penta-, and hexacoordinate spirocyclic phosphoranes that involve...
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Americium
Americium, element 95, was discovered in 1944–45 by Seaborg et al. (1950) at the Metallurgical Laboratory of the University of Chicago as a product...
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Organoboron(III) and organolead(IV) complexes as antimicrobial and antimycobacterial agents: Synthetic, structural, and biological aspects
Phenylboron(III) and triorganolead(IV) derivatives of the types PhB(OH)(DTCZ), PhB(DTCZ) 2 , and Ph 3 Pb(DTCZ) (where DTCZ − is the anion of a...
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Plutonium
The element plutonium occupies a unique place in the history of chemistry, physics, technology, and international relations. After the initial...
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Molecular Spectroscopy and Reactions of Actinides in the Gas Phase and Cryogenic Matrices
In this chapter we review the spectroscopic data for actinide molecules and the reaction dynamics for atomic and molecular actinides that have been...
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Complexes of dirhodium(II) carboxylates with calix[4]resorcinarenes functionalized at the upper and lower rim of the molecule with P,N-containing Fragments
The features of the reaction between dirhodium(II) carboxylate and calix[4]resorcinarenes modified with various type functional groups at the upper...
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Reaction of phosphorus pentachloride with 2,6-dichloro-4-phenylbenzo[e][1,2λ5]oxaphosphinine 2-oxide. Synthesis and steric structure of 2,2,6-trichloro-4-phenylbenzo[e][1,2λ5]oxaphosphinin-2-ylium hexachlorophosphate
2,2,2,6-Tetrachloro-4-phenylbenzo[ e ][1,2]oxaphosphinine and 2,2,6-trichloro-4-phenylbenzo[ e ][1,2λ 5 ]-oxaphosphinin-2-ylium hexachlorophosphate were...
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The Chemistry of Ruthenium Oxidation Complexes
This chapter introduces the topic and scope of the book and principally concerns the basic preparation, physical and chemical properties of Ru-based...
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Interplay of thermochemistry and Structural Chemistry, the journal (volume 18, 2007) and the discipline
In this study, we relate the contents of the journal Structural Chemistry for the calendar year 2007 and thermochemistry. The year’s articles were...
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Chlorinations of derivatives of 2,2,2-trichlorobenzo-1,3,2-dioxaphospholes
By 31 P, 13 C, 13 C-{ 1 H}, and 1 H NMR spectroscopy the chlorination of 4-and 5-methyl-2,2,2-trichlorobenzo-1,3,2-dioxaphosphols was shown to provide in...
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Theoretical design of planar systems with hypercoordinate p elements of the second period in a nonmetallic environment
Theoretical approaches to stabilization and design of nonclassical compounds containing p elements of the second period (B, C, N, O, F) in a...
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Microwave-assisted synthesis of nitrogen-sulfur and nitrogen-oxygen donor ferrocene-containing ligands and their organotitanium(IV) and organozirconium(IV) complexes
The synthetic routes and spectroscopic studies of organotitanium(IV) and organozirconium(IV) complexes derived from azomethines,...