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Synthesis and structure of antimony complexes [Ph3AmP] +2 [Sb2I8 · 2DMSO]2−, [Ph3PrP] +2 [Sb2I8 · C4H8O2]2−, and [(HOCH2CH2)3NH] +4 [Sb4I16]4−

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Abstract

The reaction of equimolar amounts of triphenylamyl- and triphenylpropylphosphonium iodides and triethanolammonium iodide with antimony iodide in dimethyl sulfoxide, dioxane, or acetone gave complexes [Ph3AmP] +2 [Sb2I8 · 2DMSO]2−, [Ph3PrP] +2 [Sb2I8 · C4H8O2]2−, and [(HOCH2CH2)3NH] +4 [Sb4I16]4−, the structure of which was established by X-ray diffraction analysis. The cations of all complexes have slightly distorted tetrahedral structure, and the antimony atoms in the anions are hexacoordinated. The crystals of the complexes have intra- and intermolecular contacts, which form the structure.

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References

  1. V. V. Sharutin, I. V. Egorova, O. A. Dorofeeva, et al., Zh. Obshch. Khim. 72(9), 1576 (2002).

    Google Scholar 

  2. V. V. Sharutin, I. V. Egorova, M. V. Levchuk, et al., Koord. Khim. 8(9), 654 (2002).

    Google Scholar 

  3. V. V. Sharutin, I. V. Egorova, O. K. Sharutina, et al., Koord. Khim. 30(12), 925 (2004).

    Google Scholar 

  4. V. V. Sharutin, I. V. Egorova, O. K. Sharutina, et al., Koord. Khim. 31(10), 791 (2005).

    Google Scholar 

  5. V. V. Sharutin, I. V. Egorova, A. P. Pakusina, et al., Zh. Obshch. Khim. 76(8), 1393 (2006).

    Google Scholar 

  6. V. V. Sharutin, I. V. Egorova, O. K. Sharutina, and E. A. Boyarkina, Koord. Khim. 34(6), 469 (2008).

    Google Scholar 

  7. G. M. Sheldrick, SADABS: Program for Empirical X-ray Absorption Correction (Bruker-Nonius, 1990–2004).

  8. G. M. Sheldrick, SHELX-97, Release 97-2 (Univ. of Göttingen, Göttingen, 1997).

    Google Scholar 

  9. S. S. Batsanov, Zh. Neorg. Khim. 36(12), 3015 (1991).

    CAS  Google Scholar 

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Authors and Affiliations

  1. Blagoveshchensk State Pedagogical University, Blagoveshchensk, Russia

    V. V. Sharutin, V. S. Senchurin, O. K. Sharutina, B. B. Kunkurdonova & A. G. Burlakova

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  1. V. V. Sharutin
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  2. V. S. Senchurin
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  3. O. K. Sharutina
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  4. B. B. Kunkurdonova
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  5. A. G. Burlakova
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Original Russian Text © V.V. Sharutin, V.S. Senchurin, O.K. Sharutina, B.B. Kunkurdonova, A.G. Burlakova, 2011, published in Zhurnal Neorganicheskoi Khimii, 2011, Vol. 56, No. 2, pp. 235–242.

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Sharutin, V.V., Senchurin, V.S., Sharutina, O.K. et al. Synthesis and structure of antimony complexes [Ph3AmP] +2 [Sb2I8 · 2DMSO]2−, [Ph3PrP] +2 [Sb2I8 · C4H8O2]2−, and [(HOCH2CH2)3NH] +4 [Sb4I16]4− . Russ. J. Inorg. Chem. 56, 197–204 (2011). https://doi.org/10.1134/S0036023611020264

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  • DOI: https://doi.org/10.1134/S0036023611020264

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