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X-ray Structure and DFT Studies of a New Square Planar Silver(I) Complex of Ketene S,S-Dithioacetal Ligand
The [AgL 2 ]ClO 4 complex, where L is ketene S,S- dithioacetal type ligand, is synthesized and characterized using elemental analysis, different...
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Copper(II) o-Iminophenolate Complexes Based on Catecholaldimines
AbstractThe exchange reactions of 4,6-di- tert- butylpyrocatechols containing in position 3 different N ‑aryliminomethyl groups (aryl is p -halophenyl;...
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Copper(II) and Zinc(II) Complexes with Heterocyclic Acid Anions and 3,5-Dimethylpyrazole: Synthesis, Structure, and Biological Properties
AbstractThe reaction of copper(II) and zinc(II) acetates with 3-furancarboxylic (HFur) and 2-thiophenecarboxylic (HTph) acids with subsequent...
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Computational Studies of Copper(II) Complexes Derived from N-Cyclohexyl-3-methoxysalicylideneimine and N-Cyclohexyl-3-ethoxysalicylideneimine
AbstractCopper(II) complexes [Cu(L I ) 2 ] and [Cu(L II ) 2 ] (HL I = N -cyclohexyl-3-methoxysalicylideneimine, HL II = N -cyclohexyl-3-ethoxysalicylideneimine)...
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Cu(II)-bis(benzoylacetonate) complexes as potential inhibitors for tubulin polymerization: synthesis, crystal structure, spectral characterization, HSA, DFT, molecular docking studies, and antioxidant activity
The reaction of 1-phenyl-1,3-butanedione, also known as benzoylacetone (bzac), with adequate copper salts (sulfate/acetate) at a molar ratio of 2:1...
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Synthesis, Ligating Properties, Thermal Behavior, Computational and Biological Studies of Some Azo-transition Metal Complexes
Synthesis of new Fe(III), Co(II), Ni(II), and Cu(II) complexes of two azo ligands; 1-(phenyldiazenyl) naphthalene-2-ol (sudan orange R, HL 1 ), and...
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Palladium Complexes of Pyrimidine-2-thiones: Synthesis, Structures, and Properties
AbstractComplexes [PdL 2 Cl 2 ] ( I ) and [PdL 2 Вr 2 ] ( II ) (L is 5-acetyl-6-methyl-4-(3-nitrophenyl)-1,2,3,4-tetrahydropyrimidine-2-thione) are synthesized...
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Influence of Heat Sources/Sinks on Unsteady Natural Convection in a Differentially Heated Enclosure
Numerical simulations were performed using the Lattice Boltzmann Method to investigate natural convection heat transfer in an annulus system. The...
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Anion Induced Synthesis and Crystal Structures of Schiff Base Copper(II) and Zinc(II) Complexes with Antibacterial Activity
AbstractTwo new mononuclear copper(II) complexes, [Cu(L a ) 2 ] ( I ) and [Cu(L a H) 2 ]Br 2 ( II ), and two new polynuclear zinc(II) complexes, [Zn 2 (L b )(CH 3 COO) 2 ...
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Synthesis, characterization, spectroscopic properties and antihypertensive activity of 4-chlorobenzaldehyde hydralazine hydrazone and its metal complexes
A hydrazone ligand, 4-chlorobenzaldehyde hydralazine hydrazone (LH), has been synthesized. Our initial attempts to synthesize Co +2 , Ni +2 , Cu +2 and Zn +2...
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Synthesis, Structure, and Properties of 2-Oxo-3-formylquinolone Acylhydrazone Containing a Trimethylammonium Fragment and also of Transition Metal Complexes Based on This Compound
AbstractThe product of 3-formyl-2-quinolone condensation with trimethylammonium chloride acethydrazide, (H 2 L + )Сl – hydrazone, was synthesized....
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THEORETICAL STUDY OF THE STRUCTURES AND ELECTRONIC CHARACTERISTICS OF In
x O (x = 2, 3) AND In4O0/–1AbstractThe clusters In x O ( x = 2, 3) and In 4 O 0/—1 arestudied using density functional theory (B3PW91). The global minima contain linear...
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Conformational Analysis of Oligomeric Models of Siloxane, Silazane and Siloxazane Ladder Polymers
Oligomeric models of linear ladder silanes, siloxanes and siloxazanes with seven repeat units consisting of four-, six-, or eight-membered rings were...
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STRUCTURE AND CATALYTIC PROPERTIES OF PALLADIUM(II) (ACETYLACETONATO- κ2O,O′)BIS(TRIS(DIETHYLAMINO)PHOSPHINE) TETRAFLUOROBORATE
AbstractThe structure of complex [Pd(acac){P(NEt 2 ) 3 } 2 ]BF 4 ( I ) is determined by XRD. In the crystal structure of I , the coordination sphere of...
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Nickel(II) carbothioate complex incorporated graphene oxide-polyvinylidene fluoride ternary composite film: Preparation, structural features, dielectric, and electrical characteristics
Graphene oxide-based materials are well known for their electrical properties. Novel ternary composite films (PVDF-GO-FK-31) were prepared by...
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Suzuki–Miyaura Cross Coupling Reaction Using Reusable Polymer Anchored Palladium Catalyst
Polystyrene anchored palladium (II) complex of 2-acetylbenzimidazole was synthesized and characterized by elemental analysis, FT-IR, UV–Vis/DRS...
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Synthesis, Characterization and Catalytic Activity of Super Acids (SO4/Fe2.04Co1.08−XNi0.88+XO4, X = 0.23) Derived from Metal Oxide by Sol–Gel Route
Many researchers have tried to synthesize solid super acids due to their many advantages over conventional liquid acids and hence, in this work,...
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β-DIKETONATE DERIVATIVES OF PLATINUM(II): PREPARATION AND PHYSICO-CHEMICAL STUDY
Abstractβ-Iminoketones H(i-thd) ( t -BuCOCH 2 NH t -Bu) and H(i-zis) ( t -BuCOCH 2 NHC(CH 3 ) 2 (OCH 3 )) and the corresponding platinum(II) complexes Pt(i-thd) 2 ( 1 )...
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Morphology dependent optical response tuning in planar square-shaped array of sodium nanoparticles
Among the plasmonic nanostructures, ordered arrangement of metal nanoparticles with inter-particle gap distances in the nanometer scale is becoming...
