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Article
Sandpaper-templated Stretchable Immunosensing Electrodes for Sub-picomolar Progesterone Detection
Female hormone detection, particularly non-invasive monitoring progesterone (P4) levels in body fluids, plays a critical role in female health management and disease diagnosis. However, the challenge still exi...
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Article
Inhibition of Cu-SSZ-13 for NH3 Selective Catalytic Reduction by K/Na Poisoning
Cu/SSZ-13 is considered to be a promising material for NH3-SCR catalysts. However, in practical applications, Cu/SSZ-13 is inevitably exposed to alkali metal deposition. In this paper, Cu/SSZ-13 molecular sieve c...
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Article
Preparation of starch-based adsorbing-flocculating bifunctional material St-A/F and its removal of active, direct and disperse dyes from textile printing and dyeing wastewater
A starch-based adsorbing-flocculating bifunctional material St-A/F is prepared via graft copolymerization with two cationic monomers DMC and DMDAAC, using a safe and clean Fenton initiating system. 13C NMR, XRD, ...
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Article
Copper(II)-Catalyzed 1,6-Hydroboration Reactions of p‑Quinone Methides Under Ligand-Free Conditions: A Sequential Methodology to gem-Disubstituted Methanols
The Cu(II) catalyzed 1,6-hydroboration reactions of para-quinone methides with B2pin2 was herein reported. The desired products were all obtained in good to excellent yields under mild conditions. Notably, the re...
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Article
Direct synthesis of Cu-containing Beta zeolite without template for selective oxidation of cyclohexane
Cu-containing Beta zeolites (Cu-Beta) are straightforwardly synthesized in a one-pot method without template, where the crucial step is the co-hydrolysis/condensation of silica source and copper salt at the mo...
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Article
Controllable Preparation of Chiral Oxazoline-Cu(II) Catalyst as Nanoreactor for Highly Asymmetric Henry Reaction in Water
A biomimetic nanoreactor of catalyst Cu(II)–PNxOy was prepared by reversible addition-fragmentation chain transfer polymerization (RAFT) starting from chiral amino acid. Characterizations of this catalyst disclos...
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Article
Amorphous Manganese–Cobalt Nanosheets as Efficient Catalysts for Hydrogen Evolution Reaction (HER)
A facile and efficient electrocatalyst for hydrogen evolution reaction (HER) to produce hydrogen is very important for future energy. In this paper, amorphous manganese–cobalt nanosheets are successfully prepa...
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Article
Cellulosic CuI Nanoparticles as a Heterogeneous, Recyclable Catalyst for the Borylation of α,β-Unsaturated Acceptors in Aqueous Media
We have demonstrated that cellulosic CuI nanoparticles could perform as an efficient heterogeneous catalyst for the synthesis of useful organoboron compounds. Desired β-borylation products were all obtained in...
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Article
Hydroxy Acid-Assisted Synthesis of Highly Dispersed Ni-NiS on CdS as Effective Photocatalyst for Hydrogen Evolution
To achieve the well-dispersed Ni–NiS dual-cocatalysts anchored CdS, the samples have been successfully constructed by a cheap and convenient method of hydroxy acid assisted hydrothermal method. Based on the co...
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Article
Rational Designed Polymer as a Metal-Free Catalyst for Hydroxylation of Benzene to Phenol with Dioxygen
Direct hydroxylation of benzene to phenol with dioxygen is a green route for synthesis of phenol. The higher bonding energies of C–H in benzene and O–O in dioxygen make metal-free catalysis a challenge. A nove...
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Article
DFT Study of Cluster Size-Dependent Structures and Properties of (HClGaN3)n (n = 1–6) Clusters
Gallium azides are potential single-source precursors for GaN-based materials. Understanding the size evolution of gallium azides clusters is useful to improve their properties in certain applications by contr...
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Article
Anticancer and Apoptotic-Inducing Effects of Rutin-Chitosan Nanoconjugates in Triple Negative Breast Cancer Cells
Cancer includes a range of diseases that arise as a result of the unregulated growth of malignant cells, which have the potential to invade or spread to other body parts. Nanoparticles and drug conjugate syste...
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Article
Ferrocene-Modified Metal–Organic Frameworks as a Peroxidase-Mimicking Catalyst
Recently, the development of enzyme-like catalysts attracts increasing attention owing to their remarkable advantages over natural enzymes. Metal organic frameworks (MOFs) are ideal candidates for building bio...
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Article
Sequential combustion separation of soil organic carbon fractions for AMS measurement of 14C and their application in fixation of carbon
A temperature stepped-combustion method for separating soil organic carbon (SOC) fractions and their 14C ages was developed to investigate SOC fixation and stability in soils. After acid-leaching, SOC was sequent...
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Article
Solid-liquid Phase Equilibria in the Process of Producing Lithium Hydroxide from Lithium Sulfate
The solid-liquid phase equilibria in the process of producing lithium hydroxide from lithium sulfate at 283.15, 298.15 and 323.15 K were studied via the isothermal solubility equilibrium method, and the solid spe...
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Article
Polydopamine-coated cellulose nanocrystals as an active ingredient in poly(vinyl alcohol) films towards intensifying packaging application potential
In this research, the dopamine self-polymerization was used to coat polydopamine (PDA) on cellulose nanocrystal (CNC) surfaces, and we integrated the functionality and structural merits of the two components i...
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Article
Modulating of facets-dependent oxygen vacancies on ceria and its catalytic oxidation performance
To study the correlation between crystal facets and oxygen vacancies, three kinds of ceria samples with various crystal facets, cube [100], rod [110] and octahedron [111], were prepared. For further comparison...
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Article
One-pot synthesis of IM-5 zeolite
IM-5 zeolite is synthesized in solutions of sodium hydroxide, sodium aluminate, and silica gel, along with N-methyl pyrrolidine and 1,5-dibromopentane by one-pot hydrothermal method. The method described in this ...
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Article
Polyyne formation via skeletal rearrangement induced by atomic manipulation
Rearrangements that change the connectivity of a carbon skeleton are often useful in synthesis, but it can be difficult to follow their mechanisms. Scanning probe microscopy can be used to manipulate a skeleta...
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Article
A Cuboidal Tetranuclear Nickel Cluster Based on O,O,N-Tridentate Schiff Base: Synthesis, Structure and Magnetic Properties
One tetranuclear nickel cluster [Ni4L4(CH3CH2OH)4] (1, H2L = N-(2-hydroxyphenyl)salicylaldimino) was synthesized by solvothermally reaction and characterized by elemental analysis, IR, TGA and X-ray single-crysta...